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Studies on ruthenium(III), rhodium(III) and iridium(III) complexes of indazoles

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Summary

New complexes of the general formula M(L)3Cl3 and M(5-AInz)2Cl3 · n H2O (where M = RuIII, RhIII and IrIII; L = indazole and 5-nitroindazole; n=1–2) have been synthesized and characterised by elemental analysis, molar conductance, magnetic susceptibility and i.r. and electronic spectral measurements. All the complexes are covalent and apparently have an octahedral geometry. The ligands are monocoordinated through the pyrrole nitrogen. From the far i.r. spectra amer configuration has been assigned to the indazole and 5-nitroindazole complexes.

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Authors and Affiliations

  1. Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University, 202001, Aligarh, India

    Saiyid A. A. Zaidi, Neelam Singhal & Arunima Lal

Authors
  1. Saiyid A. A. Zaidi
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  2. Neelam Singhal
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  3. Arunima Lal
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Zaidi, S.A.A., Singhal, N. & Lal, A. Studies on ruthenium(III), rhodium(III) and iridium(III) complexes of indazoles. Transition Met Chem 4, 133–136 (1979). https://doi.org/10.1007/BF00618841

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  • DOI: https://doi.org/10.1007/BF00618841

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