Transition Metal Chemistry

, Volume 8, Issue 1, pp 46–48 | Cite as

Five coordinate complexes of the type Rh(SnCl3)(NBD)L2

  • Rafael Usón
  • Luis A. Oro
  • Josefa Reyes
  • Daniel Carmona
  • Pascual Lahuerta
Full Papers


Several new rhodium complexes of general formulation Rh(SnCl3)(NBD)L2 (L=P(OMe)3, P(OMe)2Ph, P(OMe)Ph2, P(OEt)3, P(OEt)2Ph, P(OEt)Ph2, P(O-i-Pr)3, P(OPh)3) have been prepared and characterized by elemental analysis and by i.r. and n.m.r. spectroscopy. The complexes show low or no conductivity in acetone solution and react with carbon monoxide (1 atm).


Spectroscopy Physical Chemistry Acetone Inorganic Chemistry Carbon Monoxide 
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Copyright information

© Verlag Chemie GmbH 1983

Authors and Affiliations

  • Rafael Usón
    • 1
  • Luis A. Oro
    • 1
  • Josefa Reyes
    • 1
  • Daniel Carmona
    • 1
  • Pascual Lahuerta
    • 2
  1. 1.Departamento de Química InorgánicaUniversidad de ZaragozaZaragozaSpain
  2. 2.Departamento de Química Inorgánica, Facultad de QuímicasUniversidad de ValenciaBurjasotSpain

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