Summary
Nitrosyl chloride has been treated with [Ni(PPh3)2X2] (X = Cl, Br, NCS or NO3) to obtain [Ni(PPh3)XCl]2 (X=Cl, Br, NCS or NO3) and [Ni(OPPh3)(SCN)Cl]2. The compounds obtained were characterised by analyses, infrared (including far i.r.) and visible spectral studies, magnetic moment and conductivity measurements and many chemical reactions. It is proposed that the compounds have a dimeric structure with a distorted tetrahedral environment around the nickel atom and chloro-bridges.
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Prasad Sarma, K., Kumar Poddar, R. Reactions of nitrosyl chloride with [Ni(PPh3)2X2] (X=Cl, Br, NCS or NO3). Transition Met Chem 8, 31–33 (1983). https://doi.org/10.1007/BF00618793
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DOI: https://doi.org/10.1007/BF00618793