Summary
Copper(II) complexes of the general composition Cu(L)X2 (X=Cl−, Br−, NO −3 , ClO −4 , MeCOO− or 0.5 SO 2−4 , L=tetradentate twelve-membered macrocyclic ligand) have been synthesised and characterised. The complexes have been characterised by elemental analysis, conductance measurements, magnetic susceptibility, i.r., electronic and electron spin resonance spectral studies. The complexes are found to have octahedral geometry except Cu(ligand)SO4 which has been assigned a five-coordinated square pyramidal geometry.
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References
N. F. Curtis and D. A. House,Chemistry and Ind., 1708 (1961); N. F. Curtis,Coord. Chem. Rev., 3, 3 (1968).
B. Bosnich, C. K. Poon and M. L. Tobe,Inorg. Chem., 4, 1102 (1965).
J. P. Coilman and P. W. Schneider,Inorg. Chem., 5, 1380 (1966).
G. A. Melson and D. H. Busch,J. Am. Chem. Soc., 86, 4834 (1964).
J. D. Curry and D. H. Busch,J. Am. Chem. Soc., 86, 592 (1964).
L. F. Lindoy and D. H. Busch,Preparative Inorganic Reactions, Ed. by W. J. Jolly,Vol. 6, John Wiley and Sons, Inc., New York, 1971.
B. N. Figgis and J. Lewis,Proc. Inorg. Chem., 6, 37 (1964).
A. Eranshaw, L. F. Larkworthy and K. C. Patel,J. Chem. Soc. A, 1339 (1969); A. B. P. Lever and E. Mantovani,Inorg. Chem., 10, 817 (1971); B. J. Hathaway,Struct. Bonding, 14, 49 (1973); Y. Nishida and S. Kida,Coord. Chem. Rev., 27, 275 (1979).
I. M. Procter, B. J. Hathaway and P. Nicholls,J. Chem. Soc. A, 1678 (1968); A. A. G. Tomilson, B. J. Hathaway, D. E. Willing and P. Nicholls,J. Chem. Soc. A, 65 (1969);J. Inorg. Nucl. Chem., 39, 417 (1977).
F. K. Kneubuhl,J. Chem. Phys., 33, 1074 (1960).
A. Abragam and M. H. L. Pryce,Proc. Roy. Soc. (London), A 206, 164 (1951).
Idem, ibid, 205, 135 (1951).
D. Poddar,Physica, 9, 709 (1942).
D. W. Smith, J. Chem. Soc., A 3108 (1970).
A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier Pub. Company, Amsterdam, p. 204 (1968).
B. J. Hathaway and D. E. Billing,Coord. Chem. Rev., 5, 143 (1970).
B. J. Hathaway,Essay in Chemistry, Ed. J. N. Bradley and R. D. Gillard, Academic Press, p. 61 (1971).
B. J. Hathaway, R. J. Dudley and P. Nicholls,J. Chem. Soc. A, 1845 (1968).
R. J. Dudley and B. J. Hathaway,J. Chem. Soc. A, 1725 (1970).
K. Nakamoto,Infrared Spectra of Coordination Compounds, John Wiley, New York (1970).
L. Sacconi,Transition Metal Chemistry, Vol. 4, Ed. R. L. Carlin (Marcel Deckker), N. Y., p. 221 (1968).
C. J. Ballhausen and C. J. Jorgenson,Kgl. Donske Videnskab Selskab. Mat. Eys. Medd., 29, 14 (1955).
R. Barbucci, A. Bencini and D. Gatteschi,Inorg. Chem., 16, 2117 (1977).
A. Bencini and D. Gatteschi,Inorg. Chem., 16, 1994 (1977).
M. F. El-Shazly, A. El-Dissowky, T. Salem and M. Osman,Inorg. Chim. Acta, 40, 1 (1980).
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Chandra, S., Sharma, K.K. Synthesis and characterization of copper(II) complexes of a macrocyclic ligand. Transition Met Chem 8, 1–3 (1983). https://doi.org/10.1007/BF00618784
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DOI: https://doi.org/10.1007/BF00618784