Transition Metal Chemistry

, Volume 7, Issue 5, pp 261–263 | Cite as

Hydrogen-deuterium exchange in tricyclohexylphosphine complexes

  • Frans G. Moers
  • Peter J. W. M. Müskens
Full Papers

Summary

The reactions of D2 with OsHCl(CO)(PCy3)2 and the deuteriation reaction with C2H5OD have been studied. The deuteriation ratios in the PCy3 ligand have been calculated. The reaction mechanism for the deuteriation in C2H5OD is discussed.

Keywords

Physical Chemistry Inorganic Chemistry Reaction Mechanism PCy3 Tricyclohexylphosphine 

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References

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Copyright information

© Verlag Chemie GmbH 1982

Authors and Affiliations

  • Frans G. Moers
    • 1
  • Peter J. W. M. Müskens
    • 1
  1. 1.Department of Inorganic ChemistryUniversity of NijmegenED NijmegenThe Netherlands

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