Transition Metal Chemistry

, Volume 7, Issue 5, pp 261–263 | Cite as

Hydrogen-deuterium exchange in tricyclohexylphosphine complexes

  • Frans G. Moers
  • Peter J. W. M. Müskens
Full Papers


The reactions of D2 with OsHCl(CO)(PCy3)2 and the deuteriation reaction with C2H5OD have been studied. The deuteriation ratios in the PCy3 ligand have been calculated. The reaction mechanism for the deuteriation in C2H5OD is discussed.


Physical Chemistry Inorganic Chemistry Reaction Mechanism PCy3 Tricyclohexylphosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. (1).
    F. G. Moers, R. W. M. ten Hoedt and J. P. Langhout,J. Inorg. Nucl. Chem., 36, 2279 (1974).Google Scholar
  2. (2).
    F. G. Moers and J. P. Langhout,Rec. Trav. Chim., 91, 591 (1972).Google Scholar
  3. (3).
    F. G. Moers, J. H. Noordik and P. T. Beurskens,Cryst. Struct. Comm., 10, 1149 (1981).Google Scholar
  4. (4).
    R. R. Ryan and G. J. Kubas,Inorg. Chem., 17, 637 (1978).Google Scholar
  5. (5).
    S. Hietkamp, D. J. Stufkens and K. Vrieze,J. Organomet. Chem., 152, 347 (1978).Google Scholar
  6. (6).
    B. R. James, M. Preece and S. D. Robinson,Inorg. Chim. Acta, 34, L 219 (1979).Google Scholar
  7. (7).
    G. G. Eberhardt, M. E. Tadros and L. Vaska,J. Chem. Soc., Chem. Comm., 290 (1972).Google Scholar

Copyright information

© Verlag Chemie GmbH 1982

Authors and Affiliations

  • Frans G. Moers
    • 1
  • Peter J. W. M. Müskens
    • 1
  1. 1.Department of Inorganic ChemistryUniversity of NijmegenED NijmegenThe Netherlands

Personalised recommendations