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Synthesis and catalytic activity of some cationic rhodium(I) complexes with substituted quinolines

Summary

The synthesis and properties of cationic complexes of the type [Rh(NBD)L2]ClO4, [Rh(NBD)L(PPh3)]ClO4 and [Rh(CO)L(PPh3)2]ClO4 (L = substituted quinolines) are described. The diolefin complexes catalyse hydrogen transfer from isopropanol to some unsaturated substrates.

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Correspondence to Rafael Usón.

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Usón, R., Oro, L.A. & Esteruelas, M.A. Synthesis and catalytic activity of some cationic rhodium(I) complexes with substituted quinolines. Transition Met Chem 7, 242–245 (1982). https://doi.org/10.1007/BF00618705

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Keywords

  • Hydrogen
  • Physical Chemistry
  • Inorganic Chemistry
  • Catalytic Activity
  • Isopropanol