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Hydrogen transfer reactions catalyzed by neutral rhodium(I) Schiff base complexes

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Summary

Hydrogen transfer reactions from 2-propanol to acetophenone or cyclohexene are catalyzed by neutral rhodium(I) complexes of the type [Rh(COD)L] and [Rh2(COD)2L′] (where L and L′ are Schiff base ligands and COD=cycloocta-1,5-diene). Some dependency of the catalytic activity on the electronic and steric properties of the ligands are discussed.

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Authors and Affiliations

  1. Departamento de Química, Universidad de Santiago de Chile, Casilla, 5659, Santiago 2, Chile

    Renato Sariego, Irma Carkovic & Manuel Martínez

  2. Facultad de Química, Pontificia Universidad Católica de Chile, Santiago, Chile

    Mauricio Valderrama

Authors
  1. Renato Sariego
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  2. Irma Carkovic
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  3. Manuel Martínez
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  4. Mauricio Valderrama
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Sariego, R., Carkovic, I., Martínez, M. et al. Hydrogen transfer reactions catalyzed by neutral rhodium(I) Schiff base complexes. Transition Met Chem 9, 106–108 (1984). https://doi.org/10.1007/BF00618586

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  • DOI: https://doi.org/10.1007/BF00618586

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