Skip to main content
SpringerLink
Log in

Cyclic substituted dithiocarbamates as ligands. Vanadium(III)and oxovanadium(IV, V) complexes

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

New vanadium(III) and oxovanadium(VI,V) dithio-carbamato complexes formulated as V(Rdtc)3, V(Rdtc)2Cl, VO(Rdtc)2, VO(Rdtc)Cl2, VO(Rdtc)2Cl and VO(Rdtc)3 (Rdtc = piperidine-, morpholine-, thiomorpholine- orN-methylpiperazinedithiocarbamate) have been characterized by elemental analyses, electrical conductance measurements, spectral (electronic and i.r.) studies and magnetic susceptibility measurements. The dithio ligands exhibit bidentate behaviour in all the complexes. The values for the ligand field parameters were determined from the electronic absorption spectra for the vanadium(III) derivatives; the nephelauxetic parameter is indicative of a weak covalency in the metal-ligand bond. The vanadium(III) tris-derivatives are suggested to have an octahedral geometry,D 3symmetry, while the complexes of oxovanadium(IV) may be five-coordinate with a tetragonalpyramidal geometry having the oxygen at the apex. Various tentative stereochemistries are proposed for the oxovanadium(V) derivatives depending on the stoichiometry of the complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Marcotrigiano, G. C. Pellacani and C. Preti,J. Inorg. Nucl. Chem., 36, 3709 (1974).

    Google Scholar 

  2. G. Marcotrigiano, G. C. Pellacani, C. Preti and G. Tosi,Bull. Chem. Soc. Jpn., 48, 1018 (1975).

    Google Scholar 

  3. C. Preti and G. Tosi,J. Inorg. Nucl. Chem., 38, 1746 (1976).

    Google Scholar 

  4. C. Preti, G. Tosi and P. Zannini,J. Inorg. Nucl. Chem., 41, 485 (1979).

    Google Scholar 

  5. C. Preti, G. Tosi and P Zannini,J. Mol. Struct., 65, 283 (1980).

    Google Scholar 

  6. C. Preti, G. Tosi and P. Zannini,Z. Anorg. allg. Chem., 469, 234 (1980).

    Google Scholar 

  7. C. Preti and G. Tosi,Z.Anorg. allg. Chem., 419, 185 (1976).

    Google Scholar 

  8. C. Preti and G. Tosi,Z. Anorg. allg. Chem., 418, 188 (1975).

    Google Scholar 

  9. C. Preti, G. Tosi and P. Zannini,J. Mol. Struct., 53, 35 (1979).

    Google Scholar 

  10. A. Giusti, C. Preti, G. Tosi and P. Zannini,J. Mol. Struct., 98, 239 (1983).

    Google Scholar 

  11. A. C. Fabretti, M. Ferrari, G. C. Franchini, A. Giusti, C. Preti and G. Tosi,Transition Met. Chem., 8, 8 (1983).

    Google Scholar 

  12. C. Preti, G. Tosi and P. Zannini,Transition Met. Chem., 4, 360 (1979).

    Google Scholar 

  13. A. Benedetti, C. Preti and G. Tosi,J. Mol. Struct., 98, 115 (1983).

    Google Scholar 

  14. C. Furlani, G. Polzonetti, C. Preti and G. Tosi,Inorg. Chim. Acta, in press.

  15. C. Furlani, G. Polzonetti, C. Preti and G. Tosi,Gazz. Chim. Ital., in press.

  16. G. Graziosi, C. Preti and G. Tosi,Transition Met. Chem., 7, 267 (1982) and refs. therein.

    Google Scholar 

  17. P. Karajannidis, D. Kessisoglou and G. Manoussakis,Chem. Chron., 6, 487 (1977).

    Google Scholar 

  18. G. Vigee and J. Selbin,J. Inorg. Nucl. Chem., 31, 3187 (1969).

    Google Scholar 

  19. G. Aravamudan, D. H. Brown and D. Venkappayya,J. Chem. Soc. (A), 2744 (1971).

    Google Scholar 

  20. B. N. Figgis and J. Lewis,Prog. Inorg. Chem., 6, 37 (1964).

    Google Scholar 

  21. A. B. P. Lever in M. F. Lappert Ed.Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.

    Google Scholar 

  22. E. König,Structure and Bonding, 9, 175 (1971).

    Google Scholar 

  23. C. K. Jorgensen,Absorption Spectra and Chemical Bonding in Complexes, Pergamon, Oxford, 1964.

    Google Scholar 

  24. H. Hartmann und C. Furlani,Z. Physik. Chem., 9, 162 (1956).

    Google Scholar 

  25. E. König, E. Lindner, I. P. Lorenz and G. Ritter,J. Inorg. Nucl. Chem., 33, 3305 (1971).

    Google Scholar 

  26. I. P. Lorenz,Inorg. Nucl. Chem. Lett., 15, 127 (1979).

    Google Scholar 

  27. Z. Karwecka,J. Coord. Chem., 9, 37 (1979).

    Google Scholar 

  28. D. C. Bradley, I. F. Rendall and K. D. Sales,J. Chem. Soc., Dalton Trans., 2228 (1973).

  29. S. Kumar and N. K. Kaushik,Gazz. Chim. Ital., 111, 57 (1981).

    Google Scholar 

  30. B. N. Figgis,Introduction to Ligand Fields, Wiley, New York, 1966.

    Google Scholar 

  31. J. Selbin,Chem. Rev., 65, 153 (1965);Coord. Chem. Rev., 1, 293 (1966).

    Google Scholar 

  32. H. J. Stoklosa, J. R. Wasson and B. J. McCormik,Inorg. Chem., 13, 592 (1974).

    Google Scholar 

  33. C. J. Ballhausen and H. B. Gray,Inorg. Chem., 1, 111 (1962).

    Google Scholar 

  34. A. Syamal,Coord. Chem. Rev., 16, 309 (1975).

    Google Scholar 

  35. B. J. McCormik,Inorg. Chem., 7, 1965 (1968).

    Google Scholar 

  36. L. R. Farmer and F. L. Urbach,Inorg. Chem., 13, 587 (1974).

    Google Scholar 

  37. C. K. Jorgensen,J. Inorg. Nucl. Chem., 24, 1571 (1962).

    Google Scholar 

  38. M. Honda, M. Komura, Y. Kawasaki, T. Tanaka and R. Okawara,J. Inorg. Nucl. Chem., 30, 2221 (1968).

    Google Scholar 

  39. G. E. Manoussakis, C. A. Tsipis and C. C. Hadjikostas,Can. J. Chem., 53, 1530 (1975).

    Google Scholar 

  40. F. Bonati and R. Ugo,J. Organomet. Chem., 10, 257 (1967).

    Google Scholar 

  41. T. N. Srivastava and V. Kumar,J. Organomet. Chem., 107, 55 (1976).

    Google Scholar 

  42. G. St. Nikolov, N. Jordanov and I. Havezov,J. Inorg. Nucl. Chem., 33, 1055 (1971).

    Google Scholar 

  43. C. O'Connor, J. D. Gilbert and G. Wilkinson,J. Chem. Soc. A, 84 (1969).

    Google Scholar 

  44. H. K. Hall,J. Am. Chem. Soc., 79, 5441 (1967).

    Google Scholar 

  45. F. A. Cotton and J. A. McCleverty,Inorg. Chem., 3, 1398 (1964).

    Google Scholar 

  46. D. Coucovanis and J. P. Fackler Jr.,Inorg. Chem., 6, 2047 (1967).

    Google Scholar 

  47. J. Selbin, H. R. Manning and C. Cessac,J. Inorg. Nucl. Chem., 25, 1253 (1963).

    Google Scholar 

  48. C. G. Barraclough, J. Lewis and R. S. Nyholm,J. Chem. Soc., 3352 (1959).

  49. P. Bukovec, S. Milicév, A. Demsár and L. Golic,J. Chem. Soc., Dalton Trans., 1802 (1981).

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Generale ed Inorganica, University of Modena, 41100, Modena, Italy

    Fabrizia Forghieri, Gianni Graziosi, Carlo Preti & Giuseppe Tosi

Authors
  1. Fabrizia Forghieri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Gianni Graziosi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Carlo Preti
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Giuseppe Tosi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Forghieri, F., Graziosi, G., Preti, C. et al. Cyclic substituted dithiocarbamates as ligands. Vanadium(III)and oxovanadium(IV, V) complexes. Transition Met Chem 8, 372–376 (1983). https://doi.org/10.1007/BF00618577

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00618577

Keywords

Search

Navigation