Summary
The catalytic activity of rhodium complexes for the hydrosilylation of substrates such as alkenes, 1,3-dienes, 1-alkynes, or ketones, is enhanced by the addition of organic oxidizing agents, such ast-butyl hydroperoxide, hydrogen peroxide, orm-chloroperbenzoic acid. Similar enhancement is found for the Group VIA hexacarbonyls in the hydrosilylation of 1,3-dienes.
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Calhoun, A.D., Lung, K.R., Nile, T.A. et al. Organic peroxide assisted transition metal hydrosilylation catalysis. Transition Met Chem 8, 365–368 (1983). https://doi.org/10.1007/BF00618575
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DOI: https://doi.org/10.1007/BF00618575