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The interaction of hexamethylenetetramine with platinum group metals

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Summary

Complexes of the geabneral formula MXn · hmta [where hmta=hexamethylenetetramine; MXn=rhodium(III), ruthenium(III) iridium(III), palladium(II), or platinum(II) halides; n=2 or 3] and other related complexes, have been prepared in aqueous or methanolic solution.

The compounds were characterized by elemental analyses, i.r. spectra and conductivity measurements.

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References

  1. G. A. Barbieri and F. Calzolari,Atti. Acad. Lincei, 19, 594 (1911); G. A. Barbieri and A. Tettamanzi,Atti. Acad. Lincei, 15, 887 (1932); G. Scagliarini and G. Tartarini,Atti. Acad. Lincei, 4, 337 (1926); G. Scagliarini and E. Brasi,Atti. Acad. Lincei, 7, 509 (1923); R. Ripan and L. Dima,Bull. Soc. Stiinte Cluj, 4, 413 (1929); A. Malaguti,Ric. Sci. Rend. 3, 1209 (1963).

    Google Scholar 

  2. G. Scagliarini and C. C. Cesari,Gazz. Chim. Ital., 64, 742 (1934).

    Google Scholar 

  3. J. Mizuno,J. Phys. Chem., 15, 1412 (1960);16, 1574 (1961).

    Google Scholar 

  4. L. Mazzarella, A. L. Kovacs, P. De Santis and A. M. Liquiri,Acta Crystallogr., 22, 65 (1967).

    Google Scholar 

  5. A. L. Kovacs and L. Mazzarella,Ric. Sci., 36, 466 (1966).

    Google Scholar 

  6. B. Viossat, P. Khodadad and N. Rodier,Bull. Soc. Chim. Fr., 69, (1981)

  7. T. G. Balicheva and I. V. Pologikh,Zhur. Neorg. Khim., 20, 3202 (1975).

    Google Scholar 

  8. P. A. Michelet, B. Viossat, P. Khodadad and N. Rodier,Acta Crystallogr. B37, 2171 (1981).

    Google Scholar 

  9. T. C. W. Mak,Acta Crys tallogr. A, Suppl. A37, C-225 0.9.4-07 (1981).

    Google Scholar 

  10. J. Pickardt,Acta Crystallogr. A, Suppl. A37, C-228 09.4-17 (1981).

    Google Scholar 

  11. M. M. Buhannic and M. G. E. Guerchais,Rev. Chim. Miner., 8, 111 (1971).

    Google Scholar 

  12. V. J. Kohout, M. H. Hvastigova, A. Amslejova, J. Gazo and L. Omelka,Z. Anorg. Allg. Chem., 434, 29 (1977).

    Google Scholar 

  13. Y. Shiro, S, Nakamura, H. Murata and H. Negita,J. Sci. Hiroshima Univ., 31, 131 (1967).

    Google Scholar 

  14. R. Mecke and H. Spiesecke,Chem. Ber., 88, 1997 (1955).

    Google Scholar 

  15. H. Negita, Y. Nishi and K. Koga,Spectrochim. Acta, 21, 2144 (1965).

    Google Scholar 

  16. G. A. Bowmaker and S. F. Hannan,Aust. J. Chem., 25, 1151 (1972).

    Google Scholar 

  17. G. A. Bowmaker and J. F. Hannan,Aust. J. Chem., 24, 2237 (1971).

    Google Scholar 

  18. I. S. Ahuja, R. Singh and C. L. Yadara,Spectrochim. Acta, 37A, 407 (1981).

    Google Scholar 

  19. N. Katsaros, J. M. Tsangaris and G. M. Tsangaris,Monatsh. Chem., 114, 27 (1983).

    Google Scholar 

  20. K. Nagase, H. Yokobayashi and K. Sone,Bull. Chem. Soc. Jpn., 49, 563 (1976).

    Google Scholar 

  21. S. C. Tripathi, S. C. Srivastava and P. K. Srivastava,Transition Met. Chem. 7, 170 (1982).

    Google Scholar 

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Katsaros, N. The interaction of hexamethylenetetramine with platinum group metals. Transition Met Chem 8, 345–348 (1983). https://doi.org/10.1007/BF00618569

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