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Synthesis and characterisation of CoII, NiII and CuII complexes of a tridentate N5 macrocyclic ligand

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Summary

A novel tridentate macrocyclic ligand was synthesised by the reaction of 2,6-dipicolinic acid hydrazide and 2,3-butanedione. Complexes with CoII, NiII and CuII are five-coordinate trigonal bipyramidal on the basis of analyses, electrical conductance, magnetic, electronic and infrared spectral studies. I.r. studies reveal that the ligand coordinates through the pyridine nitrogen and the amido-nitrogen.

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Authors and Affiliations

  1. Department of Chemistry, Meerut College, 250001, Meerut, India

    Vidya B. Rana, Suraj P. Ratra, Dharam P. Singh & Mahendra P. Teotia

Authors
  1. Vidya B. Rana
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  2. Suraj P. Ratra
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  3. Dharam P. Singh
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  4. Mahendra P. Teotia
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Rana, V.B., Ratra, S.P., Singh, D.P. et al. Synthesis and characterisation of CoII, NiII and CuII complexes of a tridentate N5 macrocyclic ligand. Transition Met Chem 10, 115–116 (1985). https://doi.org/10.1007/BF00618463

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  • DOI: https://doi.org/10.1007/BF00618463

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