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An x-ray photoelectron spectroscopic study of some nickel(II) tetraaza macrocyclic complexes

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Summary

X-ray photoelectron spectra (XPS) of the Ni(2 p3/2, 1/2), N(1s) and Cl(2p) core levels for seven nickel(II) tetraaza macrocyclic complexes and three related macrocycles of the basic cyclam and corrin ring structures are reported. Relative satellite intensities for the Ni(2p3/2) level are also reported, where observed. The binding energy data for the core levels are interpreted in terms of structural features of these complexes, such as: (i) the conformation of the macrocyclic ring and the concomitant isomerism possibilities, (ii) the existence of “cluster-ions”, formed as a consequence of hydrogen bonding between macrocyclic cation and counter-ion, and (iii) the coordination number of nickel in these complexes. Additional information of chemical significance, which is derived from the binding energy data, concerns the magnetic properties of the complexes and an estimate of the degree of metal-ligand covalency.

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References

  1. L. J. Matienzo, L. I. Yin, S. O. Grim and W. E. Swartz Jr.,Inorg. Chem., 12, 2762 (1973).

    Article  CAS  Google Scholar 

  2. L. J. Matienzo, W. E. Swartz Jr. and S. O. Grim,Inorg. Nucl. Chem. Lett., 8, 1085 (1972).

    Article  CAS  Google Scholar 

  3. S. O. Grim, L. J. Matienzo and W. E. Swartz Jr.,J. Am. Chem. Soc., 94, 5116 (1972).

    Article  CAS  Google Scholar 

  4. C. A. Tolman, W. M. Riggs, W. J. Linn, C. M. King and R. E. Wendt,Inorg. Chem., 12, 2770 (1973).

    Article  CAS  Google Scholar 

  5. K. Siegbahn, C. Nordling, G. Johannson, J. Hedman, P. F. Heden, K. Hamrin, U. Gelius, T. Bergmark, I. O. Werme, R. Manne and Y. Baer,ESCA Applied to Free Molecules, North Holland, Amsterdam, (1969).

    Google Scholar 

  6. C. Furlani,Coord. Chem. Rev., 43, 355 (1982) and refs. therein.

    Article  CAS  Google Scholar 

  7. L. J. Matienzo and S. O. Grim,Inorg. Nucl. Chem. Lett., 9, 731 (1973).

    Article  CAS  Google Scholar 

  8. M. Seno, S. Tsuchiya and S. Ogawa,J. Am. Chem. Soc., 99, 3014 (1977).

    Article  CAS  Google Scholar 

  9. K. Sakata, M. Hashimoto, N. Tagami and Y. Murakami,Bull. Chem. Soc., Jpn., 53, 2262 (1980).

    Article  CAS  Google Scholar 

  10. D. H. Karweik and N. Winograd,Inorg. Chem., 15, 2336 (1976).

    Article  CAS  Google Scholar 

  11. K. B. Yatsimirskii, V. V. Nemoshkalenko, V. G. Aleshin, Y. D. Lampeka and A. G. Kol'chinskii,Doklady. Chem., 245, 127 (1979).

    Google Scholar 

  12. K. B. Yatsimirskii,Theor. and Exp. Chem., 19, 137 (1984).

    Article  Google Scholar 

  13. K. B. Yatsimirskii, Y. D. Lampeka, V. V. Nemoshkalenko and R. M. Prokopenko,Theor. and Exp. Chem., 19, 302 (1984).

    Article  Google Scholar 

  14. W. L. Jolly and W. B. Perry,Inorg. Chem., 13, 2686 (1974).

    Article  CAS  Google Scholar 

  15. W. L. Jolly and W. B. Perry,J. Am. Chem. Soc., 95, 5442 (1973).

    Article  CAS  Google Scholar 

  16. W. L. Jolly,Coord. Chem. Rev., 13, 47 (1974).

    Article  CAS  Google Scholar 

  17. W. B. Perry and W. L. Jolly,Inorg. Chem., 13, 1211 (1974).

    Article  CAS  Google Scholar 

  18. N. F. Curtis, Coord.Chem. Rev., 3, 3 (1968).

    Article  CAS  Google Scholar 

  19. G. Lesnewski,MSc. Thesis, La Trobe University, Melbourne, Australia (1978).

    Google Scholar 

  20. A. Jeleniewski,Honours Thesis, La Trobe University, Melbourne, Australia (1978).

    Google Scholar 

  21. S. P. Roe,Honours Thesis, La Trobe University, Melbourne, Australia (1979).

    Google Scholar 

  22. S. P. Roe, P. G. Cullis, P. J. Derrick and J. O. Hill,Aust. J. Chem., 35, 287 (1982).

    Article  CAS  Google Scholar 

  23. P. C. Kemeny, A. D. McLachlan, F. L. Battye, R. T. Poole, R. C. G. Leckey, J. Liesegang and J. G. Jenkin,Rev. Sci. Instrum., 44, 1197 (1973).

    Article  CAS  Google Scholar 

  24. T. L. Barr,J. Phys. Chem., 82, 1801 (1978).

    Article  CAS  Google Scholar 

  25. N. F. Curtis,J. Chem. Soc., 4109 (1963).

  26. D. C. Frost, A. Ishitani and C. A. McDowell,Mol. Phys., 24, 861 (1972).

    Article  CAS  Google Scholar 

  27. L. G. Warner, N. R. Rose and D. H. Busch,J. Am. Chem. Soc., 90, 6938 (1968).

    Article  CAS  Google Scholar 

  28. E. K. Barefield and F. Wagner,Inorg. Chem., 12, 2435 (1973).

    Article  CAS  Google Scholar 

  29. E. K. Barefield and D. H. Busch,Inorg. Chem., 10, 1216 (1971).

    Article  Google Scholar 

  30. B. J. Hathaway and A. E. Underhill,J. Chem. Soc., 309 (1961).

  31. S. C. Tang, G. N. Weinstein and R. H. Holm,J. Am. Chem. Soc., 95, 613 (1973).

    Article  CAS  Google Scholar 

  32. S. C. Tang, S. Koch, G. N. Weinstein, R. W. Lane and R. H. Holm,Inorg. Chem., 12, 2589 (1973).

    Article  CAS  Google Scholar 

  33. A. A. Bakke, H. W. Chen and W. L. Jolly,J. Electron Spectrosc. Relat. Phenom., 20, 333 (1980).

    Article  CAS  Google Scholar 

  34. K. S. Kim and R. E. Davis,J. Electron Spectrosc. Relat. Phenom., 1, 251 (1972).

    Article  Google Scholar 

  35. K. S. Kim,J. Electron Spectrosc. Relat. Phenom., 3, 217 (1974).

    Article  CAS  Google Scholar 

  36. M. A. Brisk and A. D. Baker,J. Electron Spectrosc. Relat. Phenom., 7, 197 (1975).

    Article  CAS  Google Scholar 

  37. T. Robert,Chem. Phys., 8, 123 (1975).

    Article  CAS  Google Scholar 

  38. M. S. Hedge, A. Srinivasan, D. D. Sarma and C. N. R. Rao,J. Electron. Spectrosc. Relat. Phenom., 25, 231 (1982).

    Article  Google Scholar 

  39. A. Ravdino and F. Battaglia,J. Electron. Spectrosc. Relat. Phenom., 20, 327 (1980).

    Article  Google Scholar 

  40. C. K. Jorgensen,Prag. Inorg. Chem., 12, 101 (1970).

    Google Scholar 

  41. H. Basch, A. Viste and H. B. Gray,J. Chem. Phys., 44, 10 (1966).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, La Trobe University, 3083, Bundoora, Victoria, Australia

    Stephen P. Roe & John O. Hill

  2. Department of Physics and Research Centre for Electron Spectroscopy, La Trobe University, 3083, Bundoora, Victoria, Australia

    John Liesegang

Authors
  1. Stephen P. Roe
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  2. John O. Hill
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  3. John Liesegang
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Roe, S.P., Hill, J.O. & Liesegang, J. An x-ray photoelectron spectroscopic study of some nickel(II) tetraaza macrocyclic complexes. Transition Met Chem 10, 100–106 (1985). https://doi.org/10.1007/BF00618459

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  • DOI: https://doi.org/10.1007/BF00618459

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