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Tetrameric copper(II) halide compounds containing (R,S)- and (S)-1-amino-2-propanolate ions

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Summary

Compounds with the composition CuXL, in which X=Cl− or Br− and L=R,S-1-amino-2-propanol andS-1-amino-2-propanol, both with deprotonated hydroxy groups, are described. Magnetic measurements strongly suggest these compounds to have a tetrameric cubane-type structure with a Cu4O4 core. The racemic and optically-active compounds show a different magnetic behaviour, most likely originating from different cluster types for the isomers. The results of the i.r., f.i.r. and e.s.r. spectra are in good agreement with the proposed cluster types.

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Authors and Affiliations

  1. Gorlaeus Laboratories, Department of Chemistry, State University Leiden, P.O. Box 9502, 2300, RA Leiden, The Netherlands

    Ger Nieuwpoort & Jan Reedijk

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  1. Ger Nieuwpoort
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  2. Jan Reedijk
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Nieuwpoort, G., Reedijk, J. Tetrameric copper(II) halide compounds containing (R,S)- and (S)-1-amino-2-propanolate ions. Transition Met Chem 7, 321–325 (1982). https://doi.org/10.1007/BF00618342

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  • DOI: https://doi.org/10.1007/BF00618342

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