Transition Metal Chemistry

, Volume 7, Issue 6, pp 313–314 | Cite as

Silver(I) diethylphosphite — Bonding mode and phosphine co-ordination compounds — a31P NMR study

  • Peter-Paul Winkler
  • Paul Peringer
Full Papers

Summary

Silver(I) complexes with the P/O ambidentate phosphito- and phosphinito-ligands are shown to adopt P-bonded structures in solution by means of31P n.m.r. spectroscopy.1J(Ag, P) of AgP(O)(OEt)2 represents the largest one bond silverphosphorus coupling constant reported so far. AgP(O)(OEt)2 forms co-ordination complexes of the stoichiometry [Ag{P(O)(OEt)2}(PBu 3 n )n], n=1, 2 or 3 which were characterized by31P n.m.r. spectroscopy.

Keywords

Spectroscopy Physical Chemistry Inorganic Chemistry Phosphine Bonding Mode 

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Copyright information

© Verlag Chemie GmbH 1982

Authors and Affiliations

  • Peter-Paul Winkler
    • 1
  • Paul Peringer
    • 1
  1. 1.Institut für Anorganische und Analytische Chemie der Universität InnsbruckInnsbruckAustria

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