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Paramagnetic complexes of platinum and palladium with acetamide

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Summary

Direct reaction of K2MCl4 (M=Pt or Pd) with acetamide leads reproducibly to complexes which can be formulated as [Pt(C2H4ON)2Cl]n and Pd4(C2H4ON)7(OH)2. Analytical and spectroscopic (i.r., n.m.r. and e.p.r.) data support the existence of polynuclear structures involving bridging ligands and partially oxidized metal centres.

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Durand, S., Jugie, G. & Laurent, JP. Paramagnetic complexes of platinum and palladium with acetamide. Transition Met Chem 7, 310–312 (1982). https://doi.org/10.1007/BF00618338

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