Transition Metal Chemistry

, Volume 7, Issue 6, pp 306–310 | Cite as

Copper(II) complexes of 2-amino-1,3,4-thiadiazole and 2-ethylamino-1,3,4-thiadiazole

  • Antonio C. Fabretti
  • Gian Carlo Franchini
  • Giorgio Peyronel
Full Papers

Summary

Some copper(II) complexes of 2-amino-1,3,4-thiadiazole (atz) and 2-ethylamino-1,3,4-thiadiazole (eatz) have been prepared and studied by electronic, i.r. and e.p.r. spectra and by magnetochemical and conductometric methods. The CuX2 · atz (X=Cl, Br) and CuCl2 · eatz complexes are presumably six-coordinate with bridging ligand molecules and asymmetrically bridging halide ions, while the CuX2 · 2 atz (X=Cl, Br) complexes probably have a flattened tetrahedral N2X2 moiety with apical interactions. The CuBr2 · 5/3 eatz · 2/3 MeOH and Cu(OAc)2 · L (L=atz or eatz) complexes have subnormal magnetic moments (1.53-1.40 B.M.). The acetato-complexes have a dimeric structure with bridging acetato-groups, copper-copper interactions and apical ligand molecules. The ligands bond principally through the amine nitrogen atom and, when bridging, also through one ring-nitrogen.

Keywords

Nitrogen Copper MeOH Nitrogen Atom Halide 

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Copyright information

© Verlag Chemie GmbH 1982

Authors and Affiliations

  • Antonio C. Fabretti
    • 1
  • Gian Carlo Franchini
    • 1
  • Giorgio Peyronel
    • 1
  1. 1.Istituto di Chimica Generale e InorganicaUniversity of ModenaModenaItaly

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