Skip to main content
SpringerLink
Log in

Inhomogeneous broadening of the spectra of organic molecules in solid state matrices

  • Published:
Journal of Applied Spectroscopy Aims and scope

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. R. I. Personov, E. I. Al'shin, L. A. Bykovskaya, and B. M. Kharlamov, “Fine structure of luminescence spectra of organic molecules with laser excitation and the nature of wide spectral bands of solid solutions,” Zh. Éksp. Teor. Fiz.,65, 1825–1836 (1973).

    Google Scholar 

  2. A. Szabo, “Laser-induced fluorescence line narrowing in ruby,” Phys. Rev. Lett.,25, 924–926 (1970).

    Google Scholar 

  3. K. K. Rebane, Elementary Theory of Vibrational Structure of Spectra of Impurity Centers in Crystals [in Russian], Nauka, Moscow (1968).

    Google Scholar 

  4. K. Rebane, P. Saari, and T. Tamm, “Nature of multiplets and phonon wing in spectra of some Shpol'skii systems,” Izv. Akad. Nauk Est. SSR, Fiz. Maten.,19, 251–254 (1970).

    Google Scholar 

  5. M. A. Krivoglaz, “Theory of broadening of a phonon-free line in a Mössbauer or optical spectrum,” Fiz. Tverd. Tela,6, 1707–1717 (1964).

    Google Scholar 

  6. K. K. Rebane and V. V. Khizhnyakov, “Theory of quasiline electron-vibrational spectra in crystals. II. Comparison of Shpol'skii and Mössbauer effects,” Opt. Spektrosk.,14, 491–494 (1963).

    Google Scholar 

  7. V. Hizhnyakov and I. Tehver, “Theory of resonant secondary radiation due to impurity centers in crystals,” Phys. Sat. Sol.,21, 755–768 (1967).

    Google Scholar 

  8. A. A. Gorokhovski and L. A. Rebane, “Temperature broadening of pure electronic line by hole burning technique,” Opt. Commun.,20, 144–151 (1977).

    Google Scholar 

  9. K. K. Rebane, “Impurity centers in crystals,” Invited lecture, Fifth Nordic Conference on Solid State Physics, Gausdal, Norway, January 1973.

  10. A. M. Stoneham, “Shapes on inhomogeneously broadened resonance lines in solids,” Rev. Mod. Phys.,41, 82–108 (1969).

    Google Scholar 

  11. A. E. Hughes, “Strain broadening of the N1 zero-phonon line in sodium chloride,” J. Phys. Chem. Solids,29, 1461–1477 (1968).

    Google Scholar 

  12. A. A. Kaplyanskii and R. B. Rozenbaum, “Concentration broadening of lines in optical spectra of ruby,“ Fiz. Tverd. Tela,13, 2623–2630 (1971).

    Google Scholar 

  13. L. A. Rebane and A. M. Freiberg, “Broadening of the phonon-free line shapes in Luminescence spectra of molecular ions O −2 in KCl,” Izv. Akad. Nauk SSSR, Ser. Fiz.,39, 1987–1992 (1975); A. M. Freiberg, “Dependence of widths of phonon-free lines in the luminescence spectrum of O −2 F on the level of excitation of local vibrations,” Fiz. Tverd. Tela,17, 3400–3401 (1975).

    Google Scholar 

  14. I. P. Ipatova, A. A. Klochikhin, A. V. Subashiev, and A. A. Maradudin, Abstracts, Selected Problems in the Theory of an Impurity Center in a Crystal [in Russian], Tallin (1970), pp. 72–76

  15. A. V. Vasil'ev and A. I. Ryskin, VI All-Union Symposium on the Spectroscopy of Crystals, Abstracts, 1979 [in Russian], Moscow (1977), pp. 72–73.

  16. A. Freiberg and L. Rebane, in: Molecular Spectroscopy of Dense Phases, M. Grosman et al., eds. (1975), pp. 495–503.

  17. T. B. Tamm, Ya. V. Kikas, and A. É. Sirk, “Measurement of the inhomogeneous distribution function for impurity centers by the method of double spectral scanning,” Zh. Prikl. Spektrosk.,24, 315–321 (1976).

    Google Scholar 

  18. A. A. Gorokhovskii, R. K. Kaarli, and L. A. Rebane, “Hole burning in the contour of a purely electronic line in Shpol'skii systems,” Pis'ma Zh. Éksp, Teor. Fiz.,20, 474–479 (1974); A. A. Gorokhovskii, R. Kaarli, and L. A. Rebane, “The homogeneous pure electronic line width in the spectrum of a H2 phthalocyanine solution in n-octane at 5°K,” Opt. Commun.,16, 282–284 (1976).

    Google Scholar 

  19. R. Avarmaa, “Effect of monochromatic excitation on the width and intensity of inhomogeneously broadened lines in the luminescence spectrum,” Izv. Akad. Nauk Eston. SSR, Fiz. Mat.,23, 238–247 (1974).

    Google Scholar 

  20. K. K. Rebane, R. A. Avarmaa, and A. A. Gorokhovskii, “Structure of phonon-free lines in inhomogeneously broadened luminescence spectra with monochromatic excitation,” Izv. Akad. Nauk SSSR, Ser. Fiz.,39, 1794–1800 (1975).

    Google Scholar 

  21. R. A. Avarmaa and A. A. Gorokhovskii, “Appearance of double structure in inhomogeneously broadened luminescence spectra of tetracene molecules in n-paraffins,” Opt. Spektrosk.,39, 266–273 (1975).

    Google Scholar 

  22. A. A. Gorokhovskii, “Hole burning in inhomogeneously broadened spectra of impurity molecules,” Dissertation, Tartu (1979).

  23. P. M. Saari and Z. B. Tamm, “Correlation of inhomogeneous structure of spectra of different electronic transitions of impurity molecules in solid matrices,” Izv. Akad. Nauk SSSR, Ser. Fiz.,39, 2321–2325 (1975).

    Google Scholar 

  24. Ya. Kikas, “Determination of inhomogeneous distribution functions and homogeneous components of spectra of impurity molecules,” Izv. Akad. Nauk Eston. SSR, Fiz. Mat.,25, 374–379 (1976).

    Google Scholar 

  25. T. H. Bolotnikova, L. A. Klimova, G. N. Nersesova, and L. F. Utkina, “Investigation of quasiline fluorescence and absorption spectra of anthracene at 77 and 4°K,” Opt. Spektrosk.,21, 420–432 (1966).

    Google Scholar 

  26. A. Gorokhovski and J. Kikas, “Inhomogeneous broadening of local vibrations in spectra of organic molecules in solid matrices,” Optics Commun.,21, 272–283 (1977).

    Google Scholar 

  27. I. Yu. Tekhver, “Inhomogeneously broadened spectrum of resonance secondary luminescence of impurity centers with monochromatic excitation,” Tartu (1977) (Preprint F-5).

  28. E. I. Al'shits, R. I. Personov, and B. M. Kharlamov, “Zero-field splitting of lines in fluorescence spectra of complex molecules,” Pis'ma Zh. Éksp. Teor. Fiz.,26, 751–755 (1977).

    Google Scholar 

  29. V. V. Hizhnyakov and I. J. Tehver, “Phase and energetic relaxation in resonant Raman scattering and hot luminescence,” J. Lumin.,18/19, 673–677 (1979).

    Google Scholar 

  30. T. Tamm and P. Saari, “Hot luminescence study of the intramolecular thermal bath of aromatics,” Chem. Phys.,40, 311–319 (1979).

    Google Scholar 

  31. A. A. Gorokhovskii and L. A. Rebane, “Temperature broadening of phonon-free lines in spectra of impurity organic molecules by the method of hole burning,” Fiz. Tverd. Tela,19, 3417–3426 (1977).

    Google Scholar 

  32. S. Voelker, R. M. Macfarlane, and A. Z. Genack, “Homogeneous line width of the S1-S0 transition of free base porphyrin in n-octane crystal as studied by photochemical hole burning,” J. Chem. Phys.,67, 1759–1765 (1977); S. Voelker and R. M. Macfarlane, “Frequency shift and dephasing of the S1-S0 transition of free base porphyrin in n-octane octane crystal as a function of temperature,” Chem. Phys. Lett.,53, 8–13 (1978).

    Google Scholar 

  33. H. De Vries and D. A. Wiersma, “Lifetime-limited photochemical hole burning in s-tetrazine benzene mixed crystals at 2°K,” Chem. Phys. Lett.,51, 565–567 (1977).

    Google Scholar 

  34. V. N. Kotlo, K. N. Solov'ev, S. F. Shkirman, and I. E. Zalesskii, “Photoinduced interconversion of luminescing centers in Shpol'skii matrices,” Izv. Akad. Nauk Beloruss. SSR, Ser. Fiz. Mat., No. 3, 99–107 (1974).

    Google Scholar 

  35. A. A. Gorokhovskii and Ya. V. Kikas, “Effects of time saturation of the hole contour in inhomogeneously broadened spectra,” Zh. Prikl. Spektrosk.,28, 832–838 (1978).

    Google Scholar 

  36. L. A. Rebane, in: Ultrafast Relaxation and Secondary Emission, Tallin (1979), pp. 89–97.

  37. A. A. Gorokhovskii and L. A. Rebane, “Determination of homogeneous characteristics of spectra of impurity molecules by the method of hole burning,” Izv. Akad. Nauk SSSR, Ser. Fiz.,44, 859–862 (1980).

    Google Scholar 

  38. B. M. Kharlamov, L. A. Bykovskaya and R. I. Personov, “Hole burning spectra. A new method for obtaining fine structure in absorption spectra of organic molecules,” Chem. Phys. Lett.,50, 407–411 (1977).

    Google Scholar 

  39. V. G. Maslov, “Hole burning in absorption spectra of solutions of photosensitive complexes of porphyrins with pyridine ions at 4.2°K,” Opt. Spektrosk.,43, 388–397 (1977).

    Google Scholar 

  40. R. A. Avarmaa and K. Kh. Mauring, “Singlet-triplet optical resonance in a solid chlorophyll solution,“ Opt. Spektrosk.,41, 670–671 (1976).

    Google Scholar 

  41. A. I. M. Dicker, M. Noort, S. Voelker, and J. H. van der Waals, “Zeeman experiments of free-base porphin by means of photochemical hole burning,” Chem. Phys. Lett.,73, 1–5 (1980).

    Google Scholar 

  42. A. Dzabo, US Patent 3,896,420, “Frequency-selective optical memory” (1975).

  43. G. Castro, D. Haarer, R. M. Macfarlane, and H. D. Trommsdorff, US Patent 4,101,976 “Frequency-selective optical data storage system“ (1978).

  44. F. Drissler, F. Craf, and D. Haarer, “Light induced proton transfer in dihydroxyanthraquinone as studied by photochemical hole burning,” J. Chem. Phys.,72, 4996–5001 (1980).

    Google Scholar 

  45. D. M. Burland and D. Haarer, “One and two-photon laser photochemistry in organic solids,” IBM J. Res. Dev.,23, 534–546 (1979).

    Google Scholar 

  46. P. M. Selzer, D. L. Huber, and D. S. Hamilton, et al., “Anomalous fluorescence line width behavior in Eu3+-doped silicate glass,” Phys. Rev. Lett.,36, 813–816 (1976).

    Google Scholar 

  47. J. Hegarty and W. M. Yen, “Optical homogeneous line widths of Pr+ in BeF2 and GeO2 glasses,“ Phys. Rev. Lett.,43, 1126–1130 (1979).

    Google Scholar 

  48. T. L. Reinecke, “Fluorescence line widths in glasses,” Solid State Commun.,32, 1103–1106 (1979).

    Google Scholar 

  49. V. Hizhnyakov and I. Tehver, “Resonant scattering of light by slowly fluctuating localized electrons,“ Phys. Status Solidi (b),95, 65–73 (1979).

    Google Scholar 

  50. B. M. Kharlamov, R. I. Personov, and L. A. Bykovskaya, “Stable ‘gap’ in absorption spectra of solid solutions of organic molecules by laser irradiation,” Opt. Commun.,12, 191–193 (1974).

    Google Scholar 

  51. J. M. Hayes and G. J. Small, “Non-photochemical hole burning and impurity site relaxation processes in organic glasses,” Chem. Phys.,27, 151–157 (1978).

    Google Scholar 

Download references

Authors
  1. L. A. Rebane
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 34, No. 6, pp. 1023–1035, June, 1981,

The author is grateful to K. K. Rebane for useful discussions.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rebane, L.A. Inhomogeneous broadening of the spectra of organic molecules in solid state matrices. J Appl Spectrosc 34, 627–637 (1981). https://doi.org/10.1007/BF00618278

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00618278

Keywords

Search

Navigation