Transition Metal Chemistry

, Volume 6, Issue 4, pp 221–223 | Cite as

Diolefin rhodium(I) complexes with tropolone and related ligands

  • Mauricio Valderrama
  • Horacio Rafart
  • Luis A. Oro
Full Papers

Summary

Rhodium(I) tropolonate and salicylaldehydate complexes of the general formula Rh(A)(diolefin) (A = tropolonate, β-iso-propyltropolonate, β-methyltropolonate and salicylaldehydate; diolefin = 1,5-cyclooctadiene, 2,5-norbornadiene and tetrafluorobenzobarrelene) have been prepared by several routes. The ability of Rh(trop)(COD) to function as an intermediate for the synthesis of other neutral and cationic rhodium(I) complexes has been studied and its hydroformylation activity has been explored briefly.

Keywords

Physical Chemistry Inorganic Chemistry General Formula Rhodium Trop 

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Copyright information

© Verlag Chemie GmbH 1981

Authors and Affiliations

  • Mauricio Valderrama
    • 1
  • Horacio Rafart
    • 1
  • Luis A. Oro
    • 2
  1. 1.Departamento de Química Inorgánica, Instituteo de Ciencias QuímicasPontificia Universidad Católica de ChileSantiagoChile
  2. 2.Departamento de Química InorgánicaUniversidad de ZaragozaZaragozaSpain

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