Summary
The binuclear iron(III) compound, Fe2Cl(OH)2(MeCO2)3 2 AcOH combines with pyridine, γ-picoline and 2,2′-bipyridyl (B) to form Fe2Cl(OH)2(AcO)3·B adducts. The secondary bases, pyrrolidine and diethylamine (RNH), on the other hand, combine with the complete elimination of chlorine to form, Fe2(NR)(OH)2(AcO)3. These products have been characterised by molecular weight, i.r. spectra, magnetic susceptibility and Mössbauer measurements.
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References
G. J. Long, W. T. Robinson, W. P. Tappmeyer and D. L. Bridges,J. Chem. Soc. Dalton Trans., 573 (1973).
J. Catterick, P. Thornton and B. W. Fitzsimmons,J. Chem. Soc. Dalton Trans., 1420 (1977).
W. M. Reiff, G. J. Long and W. A. Baker, Jr.,J. Am. Chem. Soc., 90, 6347 (1968).
W. M. Reiff, W. A. Baker, Jr. and N. E. Erickson,J. Am. Chem. Soc., 90, 4794 (1968).
A. V. Khedekar, J. Lewis, F. F. Mabbs and H. Weigold,J. Chem. Soc. A, 1561 (1967).
V. K. Garg, P. G. David, T. Matsuzawa and T. Shinjo,Bull. Chem. Soc. Jpn., 48, 1933 (1975).
R. C. Paul, R. C. Narula, S. Kaur and S. K. Vasisht,Transition Met. Chem., 1, 284 (1976).
R. C. Paul, R. C. Narula and S. K. Vasisht,Transition Met. Chem., 3, 35 (1978).
N. N. Greenwood and K. Wade,J. Chem. Soc., 1130 (1960).
N. S. Gill, R. H. Nuttall, D. E. Scaife and D. W. A. Sharp,J. Inorg. Nucl. Chem., 18, 79 (1961).
L. Doretti, S. Sitran, P. Zanella and G. Faraglia,Inorg. Nucl. Chem. Lett., 9, 7 (1973).
D. E. Earls, R. C. Axtmann, Y. Hazony and I. Lefkowitz,J. Phys. Chem. Solids, 29, 1859 (1968).
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Vasisht, S.K., Narula, R.C. Binuclear iron(III) acetates. Transition Met Chem 7, 95–96 (1982). https://doi.org/10.1007/BF00618191
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DOI: https://doi.org/10.1007/BF00618191