Transition Metal Chemistry

, Volume 7, Issue 2, pp 85–89 | Cite as

New cationic and anionic tetracoordinate nickel(I) complexes

  • Manuel Gómez
  • Pascual Royo
Full Papers

Summary

The preparation, structural study and chemical behaviour of new cationic, monoanionic and dianionic tetracoordinate nickel(I) complexes of the types: [NiL4][BPh4] (L=PPh3, AsPh3 or SbPh3), [PR4][NiX2L2] (X=Cl, Br or I; L=PPh3, AsPh3 or SbPh3 and [PR4]+=PPh4, Ph3PCH2Ph or Ph3PEt) and [PR4]2[NiX3L] (X=Cl, Br or I; L=PPh3 and [PR4]+=PPh4 or PPh3CH2Ph) are described.

Keywords

Physical Chemistry Nickel Inorganic Chemistry PPh3 Structural Study 

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Copyright information

© Verlag Cehmie Gmbh 1982

Authors and Affiliations

  • Manuel Gómez
    • 1
  • Pascual Royo
    • 1
  1. 1.Departamento de Quimica Inorgánica, Facultad de CienciasUniversidad de Alcalá de HenaresAlcalá de Henares, MadridSpain

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