Transition Metal Chemistry

, Volume 7, Issue 4, pp 202–203 | Cite as

Kinetics of acid and base catalysed hydrolysis ofcis-α- andcis2-[Co(trien)(aniline)Cl]2+ cations

  • Nayan K. Mohanty
  • Rabindra K. Nanda
Full Papers

Summary

The rate of hydrolysis of the title cations obey the rate law:-d ln[Complex]/dt=kobs=k0+k1[OH] in the range: 1≤pH≤3. The rate and activation parameters for acid and base hydrolysis (k0 and k1 paths respectively) are reported in the 40–60 °C range.

Keywords

Physical Chemistry Hydrolysis Inorganic Chemistry Aniline Activation Parameter 

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Copyright information

© Verlag Chemie GmbH 1982

Authors and Affiliations

  • Nayan K. Mohanty
    • 1
  • Rabindra K. Nanda
    • 1
  1. 1.Department of ChemistryUtkal UniversityBhubaneswarIndia

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