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Journal of Applied Electrochemistry

, Volume 7, Issue 6, pp 511–515 | Cite as

Effect of electrolyte composition on the properties of mercury electrochemical coulometers

  • J. Kotowski
  • Z. Koczorowski
Article

Abstract

The results of studies on mercury capillary coulometers containing acidified electrolyte solutions (fluoroborate or perchlorate) or neutral solutions are presented. The effects of the solution composition on the coulometer properties such as internal resistance, current yield, and electrochemical stability are discussed. It has been shown that the solutions of mercury salts which contain fluoroboric or perchloric acid are more advantageous for use as mercury coulometer electrolytes than the iodide solutions used hitherto.

The mercury capillary coulometers which are discussed here are widely used as electrochemical integrators and as the working time meters of electrical instruments in laboratories and in industry.

Keywords

Physical Chemistry Mercury Iodide Perchlorate Electrolyte Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd. 1977

Authors and Affiliations

  • J. Kotowski
    • 1
  • Z. Koczorowski
    • 1
  1. 1.Laboratory of Electrochemical Elements, Institute of Fundamental Problems of ChemistryWarsaw UniversityWarsawPoland

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