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Electrically active paramagnetic centres at Si-SiO2 interfaces

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Abstract

Spin-dependent resonance (SDR) measurements show several paramagnetic centres at silicon-oxide interfaces after room temperature oxide growth. The density of centres is about 1011 cm−2, and increases with the thickness of the oxide at a similar rate. Upon heating in N2 in the range 100–400 K the signals reduce, but recover logarithmically with time upon standing in air. They are ascribed to hydrogen or hydrogen containing species which diffuse through the oxide to the interface.

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References

  1. G.Mendz, D.Haneman: J. Phys. C11, L197-L203 (1978)

    Google Scholar 

  2. G.Mendz, D.Haneman: J. Phys. C13, 6737–6760 (1980)

    Google Scholar 

  3. D.J.Lepine: Phys. Rev.B6, 436–441 (1972)

    Google Scholar 

  4. A.G.Revesz, B.Goldstein: Surf. Sci.14, 361–374 (1969)

    Google Scholar 

  5. Y.Nishi: Jpn. J. Appl. Phys.10, 52–62 (1971)

    Google Scholar 

  6. I.Shiota, N.Miyamoto, J.Nishizawa: Surf. Sci.36, 424–429 (1973)

    Google Scholar 

  7. I.Shiota, N.Miyamoto, J.Nishizawa: Jpn. J. Appl. Phys. (Suppl. 2, Part 2), 417–420 (1974)

    Google Scholar 

  8. P.J.Caplan, J.N.Helbert, B.E.Wagner, E.H.Poindexter: Surf. Sci.54, 33–42 (1976)

    Google Scholar 

  9. P.J.Caplan: InMagnetic Resonance in Colloid and Interface Science, ed. by H.A.Resing and C.F.Wade (American Chemical Society, Washington D.C. 1976) pp. 173–181

    Google Scholar 

  10. E.H.Poindexter, E.R.Ahlstrom, P.J.Caplan: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 227–231

    Google Scholar 

  11. W.Wintruff, R.Herrling, H.J.Tiller: Chem. Phys. Lett.38, 524–528 (1976)

    Google Scholar 

  12. H.J.Tiller, P.Busack, M.Kispert, F.W.Breitbarth: Krist. Tech.12, 734–749 (1977)

    Google Scholar 

  13. H.J.Tiller, G.Rudakoff: Chem. Phys. Lett.62, 312–316 (1979)

    Google Scholar 

  14. I.Shiota, N.Miyamoto, J.Nishizawa:Solid Films and Surfaces (North-Holland, Amsterdam 1979) pp. 649–654

    Google Scholar 

  15. J.Ruzyllo, I.Shiota, N.Miyamoto, J.Nishizawa: J. Electrochem. Soc.123, 26–29 (1976)

    Google Scholar 

  16. G.Mendz, D.J.Miller, D.Haneman: Phys. Rev. B12, 5246–5251 (1979)

    Google Scholar 

  17. G.Mendz, D.Haneman: Solid State Commun.33, 657–661 (1980)

    Google Scholar 

  18. T.M.Buck: InThe Surface Chemistry of Metals and Semiconductors, ed. by H.C.Gatos (John Wiley & Sons, New York 1960) pp. 107–135

    Google Scholar 

  19. R.Stickler, G.R.Booker: J. Electrochem. Soc.109, 734–748 (1962)

    Google Scholar 

  20. R.L.Hopkins: Phys. Rev.98, 1567 (1955)

    Google Scholar 

  21. D.Baker, H.Yemm: J. Appl. Phys.8, 302–303 (1957)

    Google Scholar 

  22. B.Lemke, D.Haneman: Phys. Rev. B17, 1893–1907 (1978)

    Google Scholar 

  23. F.Lukes: Surf. Sci.30, 91–100 (1972)

    Google Scholar 

  24. H.Robbins, B.Schwartz: J. Electrochem. Soc.106, 505–508 (1959)

    Google Scholar 

  25. H.Robbins, B.Schwartz: J. Electrochem. Soc.107, 108–111 (1960)

    Google Scholar 

  26. B.Schwartz, H.Robbins: J. Electrochem. Soc.108, 365–372 (1961)

    Google Scholar 

  27. J.F.Wagner, C.W.Wilsem: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 373–378

    Google Scholar 

  28. F.J.Grunthaner, J.Maserjian: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 389–395

    Google Scholar 

  29. E.H.Nicollian, A.Goetzberger, C.N.Berglund: Appl. Phys. Lett.15, 174–177 (1969)

    Google Scholar 

  30. E.H.Nicollian, C.N.Berglund, P.F.Schmidt, J.M.Andrews: J. Appl. Phys.42, 5654–5664 (1971)

    Google Scholar 

  31. D.J.DiMaria: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 160–178

    Google Scholar 

  32. D.L.Griscom: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 232–252

    Google Scholar 

  33. A.G.Revesz: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 222–226

    Google Scholar 

  34. C.M.Svensson: InThe Physics of SiO2 and Its Interfaces, ed. by S.T.Pantelides (Pergamon Press, New York 1978) pp. 328–332

    Google Scholar 

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On leave at: Xerox, Palo Alto Research Center, Palo Alto, CA 94304, USA

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Mendz, G., Haneman, D. Electrically active paramagnetic centres at Si-SiO2 interfaces. Appl. Phys. A 26, 87–92 (1981). https://doi.org/10.1007/BF00616654

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