Journal of Applied Electrochemistry

, Volume 6, Issue 5, pp 411–415 | Cite as

A Cu(I) ion conductor obtained by replacement of Ag(I) in α-AgI

  • J. C. Bazán
  • J. A. Schmidt
Article

Abstract

A solid conductor for Cu(I) was obtained by introducing Cu(I) into the high temperature form of AgI. The cationic transport number is practically one with negligible electronic conduction. The formula of the compound may be expressed by Ag(1−x)Cu x I withx varying with the temperature.

Keywords

Physical Chemistry Electronic Conduction Temperature Form Cationic Transport Transport Number 

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References

  1. [1]
    B. B. Owens, ‘Electrochemistry and Electrochemical Engineering,’ Vol. 8, Interscience Pub, 1971.Google Scholar
  2. [2]
    R. D. Armstrong, R. S. Bulner and T. Dickinson, ‘Fast Ion Transport in Solids’, (Ed. Van Gool), North Holland, Amsterdam, (1973) p. 269.Google Scholar
  3. [3]
    T. Takahashi, O. Yamamoto and S. Ikeda.J. Electrochem. Soc. 120 (1973) 1431.Google Scholar
  4. [4]
    B. Scrosati.J. Electrochem. Soc. 120 (1973) 519.Google Scholar
  5. [4a]
    B. Scrosati, G. Pistoia, M. Lazzari and L. P. Bicelli,J. Appl. Electrochem. 4 (1974) 201.Google Scholar
  6. [5]
    W. Jost, ‘Diffusion in Solids, Liquids, Gases’, Academic Press, New York (1960), p. 198.Google Scholar
  7. [6]
    J. Nölting.Ber. Bunsenges. 68 (1964) 932.Google Scholar
  8. [7]
    J. B. Wagner and C. Wagner.J. Chem. Phys. 26 (1957) 1597.Google Scholar
  9. [8]
    C. Wagner, International Committee of Electrochemical Thermodynamics and Kinetics, Proc. 7th Meeting Lindau 1955, Butterworth Scientific Publications. London (1957) 361.Google Scholar
  10. [9]
    B. Ilschner.J. Chem. Phys. 28 (1958) 1109.Google Scholar

Copyright information

© Chapman and Hall Ltd. 1976

Authors and Affiliations

  • J. C. Bazán
    • 1
  • J. A. Schmidt
    • 1
  1. 1.Laboratorio de Fisicoquimica, Departmento de Quimica e Ingenieria QuimicaUniversidad National del Sur.Bahia BlancaArgentina

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