Studies in Kolbe electrosynthesis. I. Electrolysis of capric acid
- 95 Downloads
A study of the various parameters affecting the Kolbe electro-synthesis reaction with capric acid has shown that amongst the water-solvent systems studied, a mixture of 30 vol.% of 2-methoxy ethanol with water is superior. The necessary conductance could be readily maintained by using potassium carbonate. The desirable conditions under which capric acid could be converted to the expected reaction product, ‘octadecane’, have been established. Continuous electrolysis was possible and yields of the order of 90% were readily achieved.
KeywordsPotassium Physical Chemistry Potassium Carbonate Capric Acid Octadecane
Unable to display preview. Download preview PDF.
- V. G. Gurjar,Chem. Ind. Development 10 (1976) 15.Google Scholar
- B. C. L. Weedeon,Quart. Rev. 6 (1952) 380.Google Scholar
- B. C. L. Weedon, ‘Advances in Organic Chemistry Methods and Results’, Vol. 1, Interscience Publishers, New York (1960).Google Scholar
- L. Eberson, ‘The Chemistry of Carboxylic Acids and Esters’, (ed. Saul Patai) Interscience Publishers, New York (1969) Ch. 2.Google Scholar
- J. Peterson,Z. Elektrochem. 12 (1906) 141.Google Scholar
- W. Schmidt, V. Schoeller and K. Eberlein,Ber. Chem. 74 (1941) 1313.Google Scholar
- J. A. Eberlein and M. Whalley, ‘A Course in Modern Technique of Organic Chemistry’, 2nd Ed., Butterworths, London (1966) pp. 179–183.Google Scholar
- Theodore Shedlovsky, ‘Electrolytes’, Proceedings of an International Symposium, Trieste (June 1959), Pergamon Press (1962) p. 146.Google Scholar