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Journal of Applied Electrochemistry

, Volume 4, Issue 1, pp 53–56 | Cite as

Anodic polarization of aluminium in organic electrolytes

  • Y. Matsuda
  • Y. ŌOuchi
  • H. Tamura
Papers

Abstract

The polarization characteristics of aluminium anodes have been studied in various organic electrolytes containing aluminium chloride. The small amount of oxide present on the metal was dissolved by an anodic pre-treatment. The charge transfer number of the overall reaction was three. The current density supported by the electrolytes decreased in the order nitromethane>acetonitrile >propylene carbonate, formamide>tetrahydrofuran. The rest potential increased in the order formamide<propylene carbonate<tetrahydrofuran<acetonitrile<nitromethane.

Keywords

Oxide Aluminium Chloride Physical Chemistry Acetonitrile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. [1]
    R. Jasinski, ‘High-Energy Batteries’, Plenum Press, New York (1967).Google Scholar
  2. [2]
    R. Jasinski,J. Electroanal. Chem.,15 (1967) 89.Google Scholar
  3. [3]
    R. Jasinski,ibid.,26 (1970) 189.Google Scholar
  4. [4]
    R. Jasinski,Electrochem. Technol.,6 (1968) 28.Google Scholar
  5. [5]
    S. G. Meibuhr,J. Electrochem. Soc.,117 (1970) 56.Google Scholar
  6. [6]
    R. F. Scarr,ibid.,117 (1970) 295.Google Scholar
  7. [7]
    M. Shaw and R. Chand, Proc. 23rd Annual Power Source Conf., p. 80 (1969).Google Scholar
  8. [8]
    R. Jasinski, L. Gaines, G. Hansen and S. Carroll, Proc. 24th Power Source Symposium, p. 98 (1970).Google Scholar
  9. [9]
    D. E. Semones and J. McCallum,ibid., p. 16 (1970).Google Scholar
  10. [10]
    J. P. Gabano, G. Gerbier and L. F. Laurent, Proc. 23rd Annual Power Source Conf., p. 80 (1969).Google Scholar
  11. [11]
    M. Eisenberg and K. Wong,ibid., p. 74 (1969).Google Scholar
  12. [12]
    C. C. Liang and P. Bro,J. Electrochem. Soc.,116 (1969) 1322.Google Scholar
  13. [13]
    R. Jasinski and B. Burrows,ibid.,116 (1969) 423.Google Scholar
  14. [14]
    L. Campanella,ibid.,118 (1971) 1905.Google Scholar
  15. [15]
    D. L. Williams, J. J. Byrne and J. S. Driscoll,ibid.,116 (1969) 2.Google Scholar
  16. [16]
    Y. Matsuda, T. Inoue, H. Yoneyama and H. Tamura,Kogyo Kagaku Zasshi (J. Chem. Soc. Japan, Ind. Chem. Sec.),74 (1971) 2205.Google Scholar
  17. [17]
    H. Alt, H. Binder, G. Klempert, A. Köhling and G. Sandstede,J. Appl. Electrochem. 2 (1972) 193.Google Scholar
  18. [18]
    T. Saito, H. Ikeda, Y. Matsuda and H. Tamura,ibid.,3 (1973) 99.Google Scholar
  19. [19]
    T. Takada and Y. Miyake, Presented at 36th Meeting of the Electrochem. Soc. Japan (1969).Google Scholar
  20. [20]
    J. A. Riddick and W. B. Bunger, ‘Organic Solvents’ 3rd Edition: ‘Techniques of Chemistry Vol.II’ Ed. A. Weissberger, Wiley-Interscience, New York (1970).Google Scholar

Copyright information

© Chapman and Hall Ltd. 1974

Authors and Affiliations

  • Y. Matsuda
    • 1
  • Y. ŌOuchi
    • 2
  • H. Tamura
    • 2
  1. 1.Department of Industrial Chemistry, Faculty of EngineeringYamaguchi UniversityYamaguchiJapan
  2. 2.Department of Applied Chemistry, Faculty of EngineeringOsaka UniversityOsakaJapan

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