Abstract
Interesting reaction phenomena occur when iron is heated in SiCl4 gas. Silicon is taken up by the metal so that layers of Fe-Si compounds are formed; at the same time, iron escapes because of the formation of a volatile chloride. This leads to characteristic configurations of pores, voids, and cracks.
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Verdonk, A.C.W., van den Broek, J.J. Reaction of iron with SiCl4 gas. Oxid Met 8, 1–9 (1974). https://doi.org/10.1007/BF00612171
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DOI: https://doi.org/10.1007/BF00612171