Journal of Applied Electrochemistry

, Volume 11, Issue 2, pp 193–196 | Cite as

Study of Ti(III) solutions in various molten alkali chlorides. II. Raman spectroscopy investigation

  • E. Chassaing
  • F. Basile
  • G. Lorthioir
Papers

Abstract

Raman spectroscopic investigation of Ti(III) solutions in various alkali metal chlorides and mixtures shows that the solvent cations affect the nature of the complex anions formed. We have studied in detail the effect of adding lithium chloride upon the anion TiCl 6 3− , which is the only species present in Ti(III) solutions in molten caesium chlorides at 700° C. At 20 mol% LiCl a new band appears in the TiCl 6 3− spectrum, and it becomes the most important one from 80% LiCl onwards. This line cannot be associated with any vibration of TiCl 6 3− nor TiCl 4 but could be attributed to the condensed form Ti2Cl 9 3− .

Keywords

Spectroscopy Chloride Lithium Raman Spectroscopy Alkali Metal 

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References

  1. [1]
    D. M. Gruen and R. L. MacBeth,Pure Appl Chem. 6 (1963) 23.Google Scholar
  2. [2]
    H. A. Øye and D. M. Gruen,Inorg. Chem. 3 (1964) 836.Google Scholar
  3. [3]
    E. Chassaing, F. Basile and G. Lorthioir,J. Appl. Electrochem. 11 (1981) 187.Google Scholar
  4. [4]
    E. Chassaing, G. Lucazeau and G. Lorthioir,Z. Anorg. Allg. Chemie 468 (1980) 235.Google Scholar
  5. [5]
    R. J. H. Clark, B. K. Hunter and D. M. Rippon,Inorg. Chem. 11 (1972) 56.Google Scholar
  6. [6]
    W. van Bronswyk, R. J. H. Clark and L. Maresca,Inorg. Chem. 8 (1969) 1395.Google Scholar
  7. [7]
    E. Wendling and R. Rohmer,Bull. Soc. Chim. France 1 (1967) 8.Google Scholar
  8. [8]
    D. H. Brown, K. R. Dixon, C. M. Livingston, R. H. Nuttall and D. W. A. Sharp,J. Chem. Soc. (1967) 100.Google Scholar
  9. [9]
    G. V. Fraser, J. M. Chalmers, V. Charlton and M. E. A. Cudby,Solid State Commun. 21 (1977) 933.Google Scholar
  10. [10]
    B. Gilbert, G. Mamantov and G. M. Begun,J. Chem. Phys. 62 (1975) 950.Google Scholar

Copyright information

© Chapman and Hall Ltd 1981

Authors and Affiliations

  • E. Chassaing
    • 1
  • F. Basile
    • 1
  • G. Lorthioir
    • 1
  1. 1.Centre d'Etudes de Chimie Métallurgique (CNRS)Vitry/SeineFrance

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