Abstract
The absorption spectra of benzophenone derivatives with donor groups have been examined and measured in alcohol and benzene at concentrations of 10−2210−5 and 10−3–10−5 mole/l respectively. The characteristics of the spectra are explained by the participation in the light absorption of conformations, in which either one or both of the rings are noncoplanar, relative to the plane of the carbonyl.
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R. S. Tsekhanskii, ZhOKh,35, 237, 1965.
R. S. Tsekhanskii, ZhOKh,35, 1264, 1965.
R. S. Tsekhanskii, Izv. vuzov, Khimiya i khim. tekhnol.,6, 252, 1963.
R. S. Tsekhanskii, ZhOKh,1, 1905, 1965.
R. N. Jones, J. Am. Chem. Soc.,67, 2127, 1945.
M. T. O'Shaugnessy and W. H. Rodebuch, J. Am. Chem. Soc.,62, 2906, 1940.
R. F. Rekker and W. T. H. Nauta, Rec. trav. chim.,73, 969, 1954.
E. A. Braude, F. Sondheimer, and W. F. Forbes, Nature,173, 117, 1954; C. D. Hedden and W. C. Brown. J. Am. Chem. Soc., 75, 3744, 1953.
Heilbron et al. (eds.) Dictionary of Organic Compounds [Russian translation], IL, Moscow,1, 637, 1949; L. M. Litvinenko, N. F. Levchenko, S. V. Tsukerman, and R. S. Cheshko, ZhOKh,29, 1470, 1959.
R. S. Tsekhanskii, Izv. vuzov, Khimiya i khim. teckhnol,4, 787, 1961.
V. A. Izmail'skii, G. V. Alekseeva, and R. S. Tsekhanskii, in collection: Some Problems of Synthesis and Uses of Dyes [in Russian], GNTIKhL, Leningrad, 76, 1956.
V. A. Izmail'skii and V. A. Glushenkov, ZhVKhO im. D. I. Mendeleeva,6, 111, 1961.
R. S. Tsekhanskii, Izv. vuzov. Khimiya i khim. tekhnol.,8, 950, 1965.
J. Estermann, Z. Physik. Chem.,B1, 134, 1928.
H. L. Donle and G. Volkert, Z. Physik. Chem.,B8, 60, 1930.
K. L. Wolf, Physik. Z.,31, 227, 1930.
D. E. Clark and S. N. Kumar, Brit. J. Appl. Phys.,7, 282, 1956; E. Bergmann, L, Engel, and H. Meyer, Ber.,65, 446, 1932.
A. Gillam and E. S. Stern, Electronic Absorption Spectra of Organic Compounds [Russian translation], IL, Moscow, 178, 1957.
C. K. Ingold, Structure and Mechanism in Organic Chemistry [Russian translation], IL, Moscow, 83, 1959; Ya. K. Syrkin, Uspeichi Khimii,28, 903, 1959.
J. N. Lewis and H. Calvin, Uspeklii Khimii,10, 32, 1941.
A. Burawoy and I. P. Gritchley, Tetrahedron,5, 340, 1959.
C. N. R. Rao, Ultraviolet and Visible Spectroscopy: Chemical Applications [Russian translation], Moscow, 1964.
R. S. Tsekhanskii and L. I. Vinogradov, ZhOKh,32, 3802, 1962.
R. S. Tsekhanskii, N. N. Zobova and V. F. Ushenina, Izv. vuzov, Khimiya i khim. tekhnol.,4, 985, 1961.
S. Samoilov and M. Dyatkina, ZhFKh,22, 1294, 1948.
G. Briegleb, Fortsch. Chem. Forschg.,1, 678, 1950.
B. M. Krasovitskii and D. G. Pereyaslova, in collection: Some Problems of Synthesis and Use of Dyes [in Russian] Leningrad, 48, 1956.
L. M. Litvinenko and N. F. Levchenko, ZhOKh,31, 562, 1961.
A. W. Hanson, Acta Cryst.,6, 32, 1953; I. Toussaint, Bull. Soc. chim. Belg,54, 319, 1945.
L. Pauling, Nature of the Chemical Bond [Russian translation] Goskhimizdat, Moscow and Leningrad, 219, 1947.
De Los F. de Tar and A. A. Kazimi, J. Am. Chem. Soc.,77, 3842, 1955.
A. N. Terenin, Photochemical Dyes [in Russian] Izd-vo AN SSSR, Moscow and Leningrad, 1947.
Heilbron et al. (eds.), Dictionary of Organic Compounds [Russian translation] IL, Moscow,1, 637, 1949.
R. S. Tsekhanskii and Yu. A. Fedorov, Uch. zap. Chuvashgospedinstituta,14, 116, 1962.
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Tsekhanskii, R.S. Absorption spectra of benzophenone derivatives containing donor groups. J Appl Spectrosc 5, 237–241 (1966). https://doi.org/10.1007/BF00605834
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DOI: https://doi.org/10.1007/BF00605834