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Chemistry of Natural Compounds

, Volume 26, Issue 1, pp 28–32 | Cite as

Transformations of 2α-hydroxy-2,6,6-trimethylbicyclo[3.1.1]-heptan-3-one under conditions of acid catalysis

  • S. S. Koval'skaya
  • N. G. Kozlov
  • M. G. Novikova
  • S. V. Shavyrin
Article
  • 38 Downloads

Abstract

The transformations of 2a-hydroxy-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one under the conditions of acid catalysis have been studied. It has been shown that this compound can be used for the synthesis of products of various structures: a bridged bicyclic lactone (1,8,8-trimethyl-2-oxabicyclo[3.2.1]octan-3-one), an aromatic compound (carvacrol), and nitrogen-containing derivatives of p-menthane such as 8-acylamino-p-menth-6-en-2-ones. The structures of the compounds synthesized were shown by the results of1H and13C NMR spectroscopies.

Keywords

Organic Chemistry Lactone Aromatic Compound Carvacrol Acid Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • S. S. Koval'skaya
  • N. G. Kozlov
  • M. G. Novikova
  • S. V. Shavyrin

There are no affiliations available

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