Journal of Applied Spectroscopy

, Volume 32, Issue 6, pp 586–589 | Cite as

Sensitized luminescence of VF5 under the action of the emission of a pulsed CO2 laser

  • V. D. Klimov
  • V. A. Kuz'menko
  • V. A. Legasov
  • T. A. Udalova


Analytical Chemistry Molecular Structure 
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Literature cited

  1. 1.
    R. V. Ambartzumian and V. S. Letokhov, “Selective dissociation of polyatomic molecules by intense infrared laser fields,” Acc. Chem. Res.,10, 61 (1977).Google Scholar
  2. 2.
    K. Y. Olszyna, E. Grunwald, P. M. Keehn, and S. P. Anderson, “Megawatt IR laser chemistry. II. Use of SiF4, as an inert sensitizer,” Tetrahedron Lett., No. 19, 1609 (1979).Google Scholar
  3. 3.
    V. D. Klimov, V. A. Kuz'menko, and V. A. Legasov, “Dissociation of PF5 and sensitized reactions of VF5 under the effects of radiation from a pulsed CO2 laser,” Zh. Fiz. Khim.,52, 2893 (1978).Google Scholar
  4. 4.
    L. V. Gurvich, G. V. Karachevtsev, V. N. Kondrat'ev, et al., Bond Energies, Ionization Potentials, and Electron Affinities [in Russian], Nauka, Moscow (1974). p. 112.Google Scholar
  5. 5.
    T. Kiang, R. C. Estler, and R. N. Zare, “Upper and lower bounds on the F5S-F bond energy,” J. Chem. Phys.,70, 5925 (1979).Google Scholar
  6. 6.
    J. M. Freses, R. E. Weston, and G. W. Flynn, “Unimolecular decomposition of cyclo-C4F8 induced by a CO2-TEA laser,” Chem. Phys. Lett.,46, 69 (1977).Google Scholar
  7. 7.
    D. Gutman, W. Braun, and W. Tsang, “Comparison of the thermal and infrared laser induced unimolecular decomposition of allyl methyl ether, ethyl acetate, and isopropyl bromide,” J. Chem. Phys.,67, 4291 (1977).Google Scholar
  8. 8.
    W. E. Farneth, G. Flynn, G. Slater, and N. J. Turro, “Time resolved infrared laser photochemistry: the methyl fluoride sensitized decomposition of tetramethyl-1, 2-dioxetane. An example of infrared laser induced electronic excitation,” J. Am. Chem. Soc.,98, 7877 (1976).Google Scholar
  9. 9.
    C. Steel, V. Starov, R. Leo, et al., “Chemical thermometers in megawatt infrared laser chemistry: the decomposition of cyclobutanone sensitized by ammonia,” Chem. Phys. Lett.,62, 121 (1979).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • V. D. Klimov
  • V. A. Kuz'menko
  • V. A. Legasov
  • T. A. Udalova

There are no affiliations available

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