Chemistry of Natural Compounds

, Volume 23, Issue 1, pp 26–28 | Cite as

Synthesis of methyl ethers of methyl (methyl α-D-glucopyranosid)uronate

  • E. V. Evtushenko
  • Yu. S. Ovodov
Article
  • 37 Downloads

Abstract

Methyl (methyl α-D-glucopyranosid)uronate (I) has been obtained by the catalytic oxidation of methyl α-D-glucopyranoside with oxygen in the presence of platinum on carbon with a yield of 31%. The partial methylation of (I) followed by preparative liquid column chromatography on silica gel has provided a convenient method of obtaining all the methyl ethers of (I) in the individual state.

Keywords

Oxygen Methyl Ether Platinum Organic Chemistry 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    P. Kovac, Carbonydr. Res.,31, 323 (1973).Google Scholar
  2. 2.
    V. I. Grishkovets, A. E. Zemlyakov, and V. Ya, Chirva, Khim. Prir. Soedin., 279 (1982).Google Scholar
  3. 3.
    A. S. Shashkov, A. F. Sviridov, O. S. Chizhov, and P. Kovac, Carbohydr. Res.,62, 11 (1978).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • E. V. Evtushenko
  • Yu. S. Ovodov

There are no affiliations available

Personalised recommendations