Abstract
Using α-guaiacylpropanone as an example, it has been shown that, in the process of peroxidase oxidation of carbonyl-containing structures, biphenyl compounds having C-C bonds in the 5-5′ positions are formed. On the basis of the results of physicochemical methods of analysis, the formation of biphenyl spatially hindered structures with screened radical centers is suggested.
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Literature cited
V. A. Strel'skii and É. I. Chupka, Khim. Prir. Soedin., No. 1, 115 (1988).
J. A. Barltrop and J. D. Koyle, Excited States in Organic Chemistry, Wiley-Interscience, New York (1977).
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O. N. Grushnikov and V. V. Elkin, Advances in and Problems of Lignin Chemistry [in Russian], Moscow (1973).
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Siberian Scientific-Research Institute of Cellulose and Cardboard, Bratsk. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 111–115, January–February, 1988.
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Strel'skii, V.A., Chupka, E.I. Enzymatic oxidation of lignin and compounds modeling it. V. Products of peroxidase oxidation of α-guaiacylpropanone. Chem Nat Compd 24, 99–101 (1988). https://doi.org/10.1007/BF00597585
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DOI: https://doi.org/10.1007/BF00597585