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Structure of oxosecodelterine

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Abstract

Periodic acid does not oxidize delterine, an alkaloid fromDelphinium ternatum. However, the further oxidation of 19-oxodelterine, obtained on oxidation by Marion's method, led to oxosecodelterine, which is a semiacetal formed through the C-7 carbonyl group and the C-10 hydroxy group. The treatment of this compound with sulfuric acid led to oxosecodemethanoldelterine.

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Literature cited

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Abu Ali ibn Sina [Avicenna] Tadzhik State Medical Institute, Dushanbe. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 104–107, January–February, 1988.

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Narzullaev, A.S., Matveev, V.M., Sabirov, S.S. et al. Structure of oxosecodelterine. Chem Nat Compd 24, 91–93 (1988). https://doi.org/10.1007/BF00597583

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  • DOI: https://doi.org/10.1007/BF00597583

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