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Metabolism of acetophenone compounds of the fungus Sportorichum pulverulentum

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Abstract

With the aim of revealing the specific reactions of biotransformation under lignolytic conditions, the metabolic transformation bySporotrichum pulverulentum of a number of acetophenone compounds not previously investigated that model fragments of the lignin molecule has been studied. It has been established that the metabolism of 4-hydroxyacetophenone 3-O-β-D-glucopyranoside takes place as a sequence of processes involving deglucosylation, the methylation of free phenolic hydroxy groups with the formation of methylated intermediates, and the further hydroxylation of the m-methylated metabolite.

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Authors
  1. O. A. Grabkina
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  2. S. A. Medvedeva
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  3. S. Z. Ivanova
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  4. V. A. Babkin
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  5. V. G. Pavlinskii
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  6. V. G. Gorokhova
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  7. L. N. Petrushenko
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Additional information

Irkutsk Institute of Organic Chemistry, Siberian Branch, USSR Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 987–902, November–December, 1987.

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Grabkina, O.A., Medvedeva, S.A., Ivanova, S.Z. et al. Metabolism of acetophenone compounds of the fungus Sportorichum pulverulentum. Chem Nat Compd 23, 752–756 (1987). https://doi.org/10.1007/BF00596660

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  • DOI: https://doi.org/10.1007/BF00596660

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