Summary
Following a brief review of the general chemical composition of wood, the present status of the chemistry of the wood hemicelluloses is summarized, with special emphasis on recent contributions. The distribution of the hemicelluloses in the various wood tissues and wood cells and over the cell wall of tracheids and fibers is discussed in somewhat more detail. In conclusion, problems still to be solved in the chemistry of wood hemicelluloses are mentioned, and an attempt is made to predict future developments in this field.
Zusammenfassung
Anschließend an eine kurze Übersicht über die gesamte chemische Zusammensetzung des Holzes folgt eine Zusammenfassung über den Stand der Chemie der Hemicellulosen des Holzes, unter besonderer Berücksichtigung neuer Veröffentlichungen. Die Verteilung von Hemicellulosen in den verschiedenen Holzgeweben, in den Holzzellen und über die Zellwände von Tracheiden und Fasern wird eingehend erörtert. Abschließend werden die noch ungelösten Fragen in der Chemie der Hemicellulosen behandelt und der Versuch gemacht, die künftige Entwicklung auf diesem Gebiet darzustellen.
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References
Wardrop, A. B., and D. E. Bland in Kratzl, K., and G. Billek (Ed.): Biochemistry of Wood. London: Pergamon Press 1959, pp. 92–116.
Goring, D. A. I., and T. E. Timell: Tappi Vol.45 (1962) p. 454.
Marx-Figini, M., and G. V. Schulz: Makromol. Chem. Vol.62 (1963) p. 49.
—: Makromol. Chem. Vol.68 (1963) p. 227.
Mühlethaler, K.: Z. Schweiz. Forstv. Vol.30 (1960) p. 55.
Frey-Wyssling, A., and K. Mühlethaler: Makromol. Chem. Vol.62 (1963) p. 25.
Wardrop, A. B., in Zimmermann, M. (Ed.): The Formation of Wood in Forest Trees. New York 1964: Academic Press, pp. 87–134.
Polglase, W. J.: Adv. Carbohydrate Chem. Vol.10 (1955) p. 283.
Roudier, A.: Assoc. tech. ind. papetière Bull. Vol.10 (1956) p. 90;12 (1958) p. 110. Bull. Soc. Chim. Biol. Vol.42 (1960) p. 1492.
Lindberg, B.: Svensk Papperstid. Vol.61 (1958) p. 675.
Hamilton, J. K., and N. S. Thompson: Pulp Paper Mag. Can.59 (1958) No. 10, p. 233. Tappi Vol.42 (1959) p. 752.
Timell, T. E., C. P. J. Glaudemans, and J. K. Gillham: Pulp Paper Mag. Can. Vol.59 (1958) No. 10, p. 242. Tappi Vol.42 (1959) p. 827.
Aspinall, G. O.: Adv. Carbohydrate Chem. Vol.14 (1959) p. 429.
Hirst, E. L.: Pure Appl. Chem. Vol.5 (1962) p. 53.
Schuerch, C.: in: B. L. Browning (Ed.): The Chemistry of Wood. New York 1963 John Wiley and Sons, pp. 191–243.
Adams, G. A.: Pulp Paper Mag. Can. Vol.65 (1964) p. T-13.
Timell, T. E.: Adv. Carbohydrate Chem. Vol.19 (1964) p. 247.
Bouveng, H. O., and B. Lindberg: Adv. Carbohydrate Chem. Vol.15 (1960) p. 53.
Lindberg, B.; Pure Appl. Chem. Vol.5 (1962) p. 67.
Timell, T. E.: Unpublished results.
Schwerin, G.: Holzforschung Vol.12 (1958) p. 43.
Gustafsson, C., P. J. Ollinmaa and J. Saarnio: Acta Chem. Scand. Vol.6 (1952) p. 1299.
Meier, H.: Acta Chem. Scand. Vol.16 (1962) p. 2275.
Hamilton, J. K., and G. R. Quimby: Tappi Vol.40 (1957) p. 781.
Jones, J. K. N., C. B. Purves and T. E. Timell: Can. J. Chem. Vol.39 (1960) p. 1059.
Van Beckum, W. G., and G. J. Ritter: Paper Trade J. Vol.104 (1937) No. 19, p. 19, 49; Vol.105 (1937) No. 18, p. 127; Vol.108 (1939) No. 7, p. 27; Vol.109 (1939) No. 22, p. 107.
Wise, L. E., M. Murphy and A. A. D'Addieco: Paper Trade J. Vol.122 (1946) No. 2, p. 35.
Poljak, A.: Angew. Chem. Vol.60 (1948) p. 45.
Timell, T. E., and E. C. Jahn: Svensk Papperstid. Vol.54 (1951) p. 831.
Klauditz, W.: Holzforschung Vol.11 (1957) p. 110.
Kürschner, K., and St. Karacsonyi: Holzforschung Vol.15 (1961) p. 107.
Karácsonyi, St.: Zh. Prikl. Khim. Vol.36 (1963) p. 895.
Haas, H., W. Schoch and U. Ströle: Papier Vol.9 (1955) p. 469.
Leopold, B.: Tappi Vol.44 (1961) p. 230.
Garegg, P. J.: Acta Chem. Scand. Vol.16 (1962) p. 1849.
Hägglund, E., B. Lindberg and J. McPhearson: Acta Chem. Scand. Vol.10 (1956) p. 1160.
Cafferty, P. D., C. P. J. Glaudemans, R. Coalson and R. H. Marchessault: Svensk Papperstid. Vol.67 (1964) p. 845.
Bouveng, H. O.: Acta Chem. Scand. Vol.15 (1961) p. 87, 96.
Dutton, G. G. S., and A. M. Unrau: Can. J. Chem. Vol.40 (1962) p. 348.
Zinbo, M., andT. E. Timell: Chem. Ind. (London) (1965).
LeBel, R. G., and D. A. I. Goring: J. Polymer Sci. C, Vol.2 (1963) p. 29.
Koshijima, T., andT. E. Timell: Unpublished results.
Horio, M., R. Imamura and H. Inagaki: Tappi Vol.38 (1955) p. 216.
Timell, T. E.: Svensk Papperstid. Vol.65 (1962) p. 435.
Glaudemans, C. P. J., and T. E. Timell: Svensk Papperstid. Vol.61 (1958) p. 1.
LeBel, R. G., D. A. I. Goring and T. E. Timell: J Polymer Sci. C, Vol.2 (1963) p. 9.
Bouveng, H. O., P. J. Garegg and B. Lindberg: Acta Chem. Scand. Vol.14 (1960) p. 742.
Marchessault, R. H., and C. Y. Liang: J. Polymer Sci. Vol.59 (1962) p. 357.
Horio, M., and R. Imamura: J. Polymer Sci. A, Vol.2 (1964) p. 627.
Marchessault, R. H., and W. J. Settineri: Polymer Letters Vol.2 (1964) p. 1047.
Yundt, A. P.: J. Am. Chem. Soc. Vol.71 (1949) p. 757. Tappi Vol.34 (1951) p. 89, 91.
Marchessault, R. H., F. F. Morehead, N. W. Walter, C. P. J. Glaudemans, andT. E. Timell: J. Polymer Sci. Vol.51 (1961) p. s66.
Wang, P. Y., H. I. Bolker and C. B. Purves: Can. J. Chem. Vol.42 (1964) p. 2434.
Timell, T. E.: Svensk Papperstid. Vol.63 (1960) p. 472.
Jones, J. K. N., L. E. Wise and J. Jappe: Tappi Vol.39 (1956) p. 139.
Meier, H.: Acta Chem. Scand. Vol.12 (1958) p. 144.
Quick, R. H.: Tappi Vol.39 (1956) p. 357.
Adams, G. A.: Svensk Papperstid. Vol.67 (1964) p. 82.
Roudier, A.: Assoc. techn. ind. papetière Bull. Vol.16 (1962) p. 343.
Ritter, G. J.: Ind. Eng. Chem. Vol.17 (1925) p. 1194.
Harlow, W. M.: Paper Trade J. Vol.109 (1939) No. 18, p. 38.
Jayme, G., and R. Wettstein: Papier-Fabr. Vol.36 (1938) p. 519.
Timell, T. E.: Tappi Vol.44 (1961) p. 88.
Marchessault, R. H., H. Holava and T. E. Timell: Can. J. Chem. Vol.41 (1963) p. 1612
Meier, H.: Acta Chem. Scand. Vol.15 (1961) p. 1381.
Glaudemans, C. P. J., and T. E. Timell: Svensk Papperstid. Vol.60 (1957) p. 869.
Abdurahman, N., G. G. S. Dutton, D. M. McLardy, K. E. Pierre, and B. I. Stephenson: Tappi Vol.47 (1964) p. 812.
Hamilton, J. K., H. W. Kircher and N. S. Thompson: J. Am. Chem. Soc. Vol.78 (1956) p. 2508.
Hamilton, J. K., E. V. Partlow and N. S. Thompson: J. Am. Chem. Soc. Vol.82 (1960) p. 541.
Jones, J. K. N., and T. J. Painter: J. Chem. Soc. (1957) p. 669; (1959) p. 573.
Vaughan, J. M., and E. E. Dickey: J. Org. Chem. Vol.29 (1964) p. 715.
Meier, H.: Acta Chem. Scand. Vol.14 (1960) p. 749.
Mills, A. R., and T. E. Timell: Can. J. Chem. Vol.41 (1963) p. 1389.
Schwarz, E. C. A., and T. E. Timell: Can. J. Chem. Vol.41 (1963) p. 1381.
Koshijima, T.: Nippon Mokuzai Gakkasishi Vol.6 (1960) p. 194.
Croon, I., and B. Lindberg: Acta Chem. Scand. Vol.12 (1958) p. 453.
Meier, H., Acta Chem. Scand. Vol.12 (1958) p. 1911.
Lindberg, B., and H. Meier: Svensk Papperstid. Vol.60 (1957) p. 785.
Vaughan, J. M., L. E. Wise and L. Borchardt: J. Org. Chem. Vol.25 (1960) p. 1837.
White, E. V.: J. Am. Chem. Soc. Vol.63 (1941) p. 2871; Vol.64 (1942) p. 302, 1507, 2838.
Bouveng, H. O., and B. Lindberg: Acta Chem. Scand. Vol.10 (1956) p. 1515;12 (1958) p. 1977.
Bouveng, H. O.: Acta Chem. Scand. Vol.13 (1959) p. 1869,1877; Vol.15 (1961) p. 78. Svensk Kem. Tidskr. Vol.73 (1961) p. 113.
Aspinall, G. O., andA. Nicolson: J. Chem. Soc. (1960) p. 2503.
Adams, G. A.: Can. J. Chem. Vol.38 (1960) p. 280.
Haq, S., and G. A. Adams: Can. J. Chem. Vol.39 (1961) p. 1563.
Urbas, B., C. T. Bishop and G. A. Adams: Can. J. Chem. Vol.41 (1963) p. 1522.
Campbell, W. G., E. L. Hirst andJ. K. N. Jones: J. Chem. Soc. (1948) p. 774.
Jones, J. K. N., and P. E. Reid: J. Polymer Sci. C, Vol.2 (1963) p. 63.
Adams, M. F., and C. Douglas: Tappi Vol.46 (1963) p. 544.
Roudier, A., andL. Eberhard: Bull. Soc. Chim. France (1963) p. 844.
Aspinall, G. O., andT. M. Wood: J. Chem. Soc. (1963) p. 1686.
Roudier: Paper presented at the International Symposium on the Chemistry and Biochemistry of Lignin, Cellulose, and Hemicelluloses, Grenobles, France, June 29 to July 4, 1964.
Bouveng, H. O., and H. Meier: Acta Chem. Scand. Vol.13 (1959) p. 1884.
Schreuder, H., andT. E. Timell: Unpublished results.
Hillis, W. W., Ed.: Wood Extractives. New York 1962: Academic Press.
Harlow, W. M., and L. E. Wise: Ind. Eng. Chem. Vol.20 (1928) p. 720.
Bailey, A. J.: Ind. Eng. Chem. Anal. Ed. Vol.8 (1936) p. 389.
Kitao, K.: Wood Research (Japan) Vol.14 (1955) p. 1, 6. Chem. Abstracts50 (1956) p. 11015.
Holmberg, C. V., and E. C. Jahn: Paper Trade J. Vol.111 (1940) No. 1, p. 33.
Treiber, E., Å. S. son Stenius and J. Rehnström: Svensk Papperstid. Vol.61 (1958) p. 55.
Roschier, R. H.: J. Ahava and U. Ilvonen: Paperi Puu, Vol.41, (1959) p. 133.
Perilä, O.: J. Polymer Sci. Vol.51 (1961) p. 19.
Perilä, O., and P. Heitto: Suomen Kemistilehti B Vol.32 (1959) p. 76.
Perilä, O., and T. Seppä: Suomen Kemistilehti B Vol.33 (1960) p. 114.
Perilä, O.: Suomen Kemistilehti B Vol.35 (1962) p. 176.
Tsvetaeva, I. P., M. K. Mukovnikova and N. I. Nikitin: Zhur. Prikl. Khim. Vol.25 (1952) p. 174.
Simson, B., andT. E. Timell: Unpublished results.
Côté, W. A. jr., andT. E. Timell: Unpublished results.
Chochieva, M. M., I. P. Tsvetaeva, M. K. Yur'eva, A. F. Zaitseva, G. A. Petropavlovskii and N. I. Nikitin: Trudy Inst. Lesa, Akad. Nauk S.S.S.R., Izuchenie Khim. Sostava Drevesiny Daursk. Listvennitsy Vol.45 (1958) p. 31. Chem. Abstracts53 (1959) p. 4439.
Zaitseva, A. F.: Trudy Inst. Leasa, Akad. Nauk S.S.S.R., Izuchenie Khim Sostava DrevesinyDaursk. Listvennitsy45 (1958) p. 50. Chem. Abstracts Vol.53 (1959) p. 4439.
Stewart, C. M., G. L. Amos and J. L. Harvey: Australian J. Biol. Sci. Vol.6 (1953) p. 21.
Stewart, C. M.: Tappi Vol.40 (1967) p. 244.
Kremers, R. E.: Tappi Vol.47 (1964) p. 292.
Haas, B. R., and R. E. Kremers: Tappi Vol.47 (1964) p. 568.
Thornber, J. P., and D. H. Northcote: Biochem. J. Vol.81 (1964) p. 449, 455.
Thornber, J. P., and D. H. Northcote: Biochem. J. Vol.82 (1962) p. 340.
Bailey, A. J.: Ind. Eng. Chem. Anal. Ed. Vol.8 (1936) p. 52.
Lange, P. W.: Svensk Papperstid. Vol.57 (1954) p. 525.
Jayme, G., and D. Fengel. Holz als Roh-Werkstoff Vol.19 (1961) p. 50. Holzforschung Vol.15 (1961) p. 98.
Sachs, I. B., I. T. Clark and J. C. Pew: J. Polymer Sci. C Vol.2 (1963) p. 203.
Meier, H.: Holz als Roh-Werkstoff Vol.13 (1955) p. 323.
Wardrop, A. B., and H. E. Dadswell: Australian J. Sci. Res. B3 (1950) p. 1; B5 (1952) p. 385.
Scurfield, G., and A. B. Wardrop: Australian J. Bot.11 (1963) p. 107.
Asunamaa, S., and P. W. Lange: Svensk Papperstid. Vol.57 (1954) p. 501.
Meier, H.: Pure Appl. Chem. Vol.5 (1962) p. 37.
Sultze, R. F. jr.: Tappi Vol.40 (1957) p. 985.
Kallmes, O.: Tappi Vol.43 (1960) p. 143.
Meier, H., and K. C. B. Wilkie: Holzforschung Vol.13 (1959) p. 177.
Meier, H.: J. Polymer Sci. Vol.51 (1961) p. 11.
Meier, H., and S. Yllner: Svensk Papperstid. Vol.59 (1956) p. 395.
Bucher, H.: Papier Vol.14 (1960) p. 542.
Liang, C. Y., K. H. Bassett, E. A. Mcginnes and R. H. Marchessault: Tappi Vol.43 (1960) p. 1017.
Meier, H.: Biochim. Biophys. Acta Vol.28 (1958) p. 229.
Frei, E., and R. D. Preston: Nature Vol.192 (1961) p. 939.
Preston, R. D.: Endevour Vol.23 (1964) p. 153.
Ranby, B. G.: Fine Structure and Reactions of Native Cellulose. Inaugural Dissertation. Grafiska Konstanstalten Tryckeri A. B., Stockholm, 1952.
Svensson, A. A.: Arkiv Kemi Vol.10 (1956) p. 729.
Painter, T. J., and C. B. Purves: Tappi Vol.43 (1960) p. 729.
Ramalingam, K. V., and T. E. Timell: Svensk Papperstid. Vol.57 (1964) p. 512.
Yean, W. Q., and D. A. I. Goring: Tappi Vol.47 (1964) p. 16.
Côté, W. A. Jr.: J. Polymer Sci. C, Vol.2 (1963) p. 201.
Merewether, J. W. T.: Holzforschung Vol.1d (1957) p. 65.
Neufeld, E. F., and W. Z. Hassid: Adv. Carbohydrate Chem. Vol.18 (1963) p. 309.
Elbein, A. D., G. A. Barber and W. Z. Hassid: J. Am. Chem. Soc. Vol.86 (1964) p. 309.
Neish, A. C., in: K. Kratzl and G. Billek, Ed.: Biochemistry of Wood. London 1959: Pergamon Press, pp. 82–91.
Rydholm, S.: Pulping Processes. New York, 1964: John Wiley and Sons.
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Timell, T.E. Recent progress in the chemistry of wood hemicelluloses. Wood Sci.Technol. 1, 45–70 (1967). https://doi.org/10.1007/BF00592255
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DOI: https://doi.org/10.1007/BF00592255