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Incorporation of tritium in unsaturated steroids: Pregnenolone-7α-H3 and progesterone-7α-H3 of very high specific activity

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Literatur

  1. Sinex, F. M.: Proc. Symposium on Tritium in Tracer Application, New York, New York, November, 1957, p. 1.

  2. Bradlow, H. L., D. K. Fukushima andT. F. Gallacher: Atomlight, September, 1959.

  3. Wilzbach, K. E.: J. Amer. Chem. Soc.79, 1013, (1957).

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  4. Dutton, H. J., andR. F. Nystrom: Proc. Symposium on Tritium in Tracer Application, New York, New York, October, 1958, p. 8.

  5. Antonucci, R., S. Bernstein, D. Giancola andK. J. Sax: J. Org. Chemistry16, 1126 (1951).

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  6. Antonucci, R., S. Bernstein, D. Giancola andK. J. Sax: Therefore, if the Oppenauer oxidation product would have contained any 5α-pregnane-3,20-dione (arising from tritium addition on the Δ5) at all, then it could not have amounted to more than 5%.

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  1. Department of Organic Chemistry, The Worcester Foundation for Experimental Biology, Shrewsbury, Mass.

    Marcel Gut & Milan Uskoković

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  1. Marcel Gut
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  2. Milan Uskoković
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Gut, M., Uskoković, M. Incorporation of tritium in unsaturated steroids: Pregnenolone-7α-H3 and progesterone-7α-H3 of very high specific activity. Naturwissenschaften 47, 40 (1960). https://doi.org/10.1007/BF00590743

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  • DOI: https://doi.org/10.1007/BF00590743

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