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Phosphonated poly(1,6-heptadiyne) derivatives prepared by metathesis polymerization for nonlinear optics

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Poly(triethyldipropargylphosphonoacetate) (TDPA), poly[(tetraethyl dipropargylmethylenediphosphonate) (TDMDP) were prepared by metathesis polymerization using transition-metal catalysts. MoCl5-based catalyst systems were more effective for the polymerization of these monomers than WCl6-based catalyst systems. Resulting polymers exhibited good solubility in common organic solvents and could be easily cast on glass plates to give thin films. Third-harmonic Maker fringe technique was used to measure third-order nonlinear susceptibility,x (3), for thin film of poly(TDPA). Thex (3) was evaluated to be 3.4x10-11 esu at incident wavelength of 1.907μm.

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Authors and Affiliations

  1. Department of Chemistry, Korea Advanced Institute of Science and Technology, 373-1 Kusung-Dong, Yusung-Gu, Taejon, Korea

    Hyung-Jong Lee, Jae-Min Oh, Sang-Jun Choi & Sam-Kwon Choi

  2. Photonic Switching Section Electronics and Telecommunications Research Institute, Daeduk Science Town, P.O. Box 8, Taejeon, Korea

    Hwan-Kyu Kim

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  1. Hyung-Jong Lee
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  2. Jae-Min Oh
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  3. Sang-Jun Choi
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  4. Hwan-Kyu Kim
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  5. Sam-Kwon Choi
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Lee, HJ., Oh, JM., Choi, SJ. et al. Phosphonated poly(1,6-heptadiyne) derivatives prepared by metathesis polymerization for nonlinear optics. Polymer Bulletin 32, 433–438 (1994). https://doi.org/10.1007/BF00587885

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  • DOI: https://doi.org/10.1007/BF00587885

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