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Poly(arylenecarbonate)s oligomers by carbonate interchange reaction of dimethyl carbonate with bisphenol-A

FAB-MS evidence for the nature of end groups in the oligomers

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Summary

Fast atom bombardment mass spectrometry (FAB-MS) has been used to identify oligomers with different end groups obtained by the carbonate interchange reaction of bisphenol-A with dimethyl carbonate and the partial methanolysis of poly(bisphenol-A carbonate)s. Based on the FAB-MS data, a reaction pathway for the formation of compounds in the synthesized oligomers is proposed.

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Authors and Affiliations

  1. Division of Polymer Chemistry, National Chemical Laboratory, 411008, Pune, India

    A. G. Shaikh & S. Sivaram

  2. Dipartimento Di Scienze Chimiche Universita' di Catania, Consiglio Nazionale delle Ricerche, Vilae A. Doria, 6, I-95125, Catania, Italy

    C. Puglisi, F. Samperi & G. Montaudo

  3. Istituto per la Chimica e Technologia dei Materiali Polimerici, Consiglio Nazionale delle Ricerche, Vilae A. Doria, 6, I-95125, Catania, Italy

    C. Puglisi, F. Samperi & G. Montaudo

Authors
  1. A. G. Shaikh
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  2. S. Sivaram
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  3. C. Puglisi
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  4. F. Samperi
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  5. G. Montaudo
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NCL communication No. 5920

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Shaikh, A.G., Sivaram, S., Puglisi, C. et al. Poly(arylenecarbonate)s oligomers by carbonate interchange reaction of dimethyl carbonate with bisphenol-A. Polymer Bulletin 32, 427–432 (1994). https://doi.org/10.1007/BF00587884

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  • DOI: https://doi.org/10.1007/BF00587884

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