Polymer Bulletin

, Volume 32, Issue 4, pp 411–417 | Cite as

Reaction behaviour of monomeric β-ketoesters

1. Synthesis and polymerization of complexes of 2-acetoacetoxyethyl methacrylate
  • Norbert Moszner
  • Ulrich Salz
  • Volker Rheinberger


Complexes of various metal salts and 2-acetoacetoxyethyl methacrylate (AAEMA) were synthesized and characterized by elemental analyses, IR and1H NMR spectroscopy. The prepared complexes are radically polymerizable. The polymer complexes can be hydrolyzed under acidic conditions yielding poly(AAEMA).


Polymer Spectroscopy Methacrylate Acidic Condition Metal Salt 
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  1. [1]
    A.R. Despic, D. Kosanovic, Makromol. Chem.29 (1959) 151.CrossRefGoogle Scholar
  2. [2]
    H. Brito, V. Brito, J. Springer, DE-OS 2659242 (1976).Google Scholar
  3. [3]
    R. Ran, D. FU, J. Macromol. Sci.-Chem.A27 (1990) 625.Google Scholar
  4. [4]
    J.R. Grawe, B.G. Bufkin, J. Coatings Technol.52 (1980) 52.Google Scholar
  5. [5]
    S. Masuda, M. Tanaka, T. Ota, J. Polym. Sci., Part A: Polym. Chem.27 (1989) 855.Google Scholar
  6. [6]
    J. Macromol. Sci.-Pure Appl. Chem.A 29 (1992) 821.Google Scholar
  7. [7]
    T. Sato, N. Morita, H. Tanaka, T. Ota, Makromol. Chem.191 (1990) 2599.Google Scholar
  8. [8]
    T. Sato, N. Morita, I. Kamiyama, H. Tanaka, T. Oda, Makromol. Chem., Rapid Commun.11 (1990) 553.Google Scholar
  9. [9]
    K. Körber, K. Ludwig, Zahnärztliche Werkstoffkunde und Technologie, G. Thieme Verlag, Stuttgart-New York 1982, 168.Google Scholar
  10. [10]
    G.M. Brauer E.E. White, M.G. Moshonas, J. Dent. Res.37 (1958) 547.PubMedGoogle Scholar
  11. [11]
    T.L. Nielsen, Acta Odont. Scand.21 (1963) 159.PubMedGoogle Scholar
  12. [12]
    N. Moszner, M. Hartmann, P. Zalusky, D. Vegh and J. Kovac: J. Macromol. Sci.-Chem.A-27 (1990) 59.Google Scholar
  13. [13]
    W. Connely, G. Moddy, R.O. Symcox, GB-Patent 1144486 (1967).Google Scholar
  14. [14]
    R. West, R. Riley, J. Inorg. Nucl. Chem.5 (1958) 295.Google Scholar
  15. [15]
    W.C. Fernelius, B.E. Bryant, Inorg. Synth.5 (1958) 295.Google Scholar
  16. [16]
    R.C. Mehrotra, R. Bohra, D.P. Gaur, Metal-β-Diketonates and Allied Derivatives, Academic, London 1978.Google Scholar
  17. [17]
    H.G. Brittain, Inorg. Chem.14 (1975) 2858.Google Scholar
  18. [18]
    H. Friebolin, Ein- und zweidimensionale NMR-Spektroskopie, VCH Verlags-gesellschaft mbH, Weinheim/Basel/Cambridge/New York 1988, 144.Google Scholar
  19. [19]
    J. Lecomte, Disc. Faraday Soc.9 (1950) 125.Google Scholar
  20. [20]
    H.F. Holtzclaw, J. Collman, J. Amer. Chem. Soc.79 (1957) 3318.Google Scholar
  21. [21]
    R. West, R. Riley, J. Inorg. Nucl. Chem.5 (1958) 295.Google Scholar
  22. [22]
    R.N. Prasad, M. Jindal, Synth. React. Inorg. Met.-Org. Chem.19 (1989) 997.Google Scholar
  23. [23]
    S. Tazuke, in: Progress in Polymer Science Japan (Ed. M. Imoto and S. Onogo), Vol. 1, Tokio/New York 1971, 69Google Scholar
  24. [24]
    P.L. Nayak, S. Lenka, J. Macromol. Sci.-Rev. Macromol. Chem.C-19 (1980) 83.Google Scholar

Copyright information

© Springer-Verlag 1994

Authors and Affiliations

  • Norbert Moszner
    • 1
  • Ulrich Salz
    • 1
  • Volker Rheinberger
    • 1
  1. 1.Ivoclar AGSchaanLiechtenstein

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