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Reaction behaviour of monomeric β-ketoesters

1. Synthesis and polymerization of complexes of 2-acetoacetoxyethyl methacrylate

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Summary

Complexes of various metal salts and 2-acetoacetoxyethyl methacrylate (AAEMA) were synthesized and characterized by elemental analyses, IR and1H NMR spectroscopy. The prepared complexes are radically polymerizable. The polymer complexes can be hydrolyzed under acidic conditions yielding poly(AAEMA).

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References

  1. A.R. Despic, D. Kosanovic, Makromol. Chem.29 (1959) 151.

    Article  Google Scholar 

  2. H. Brito, V. Brito, J. Springer, DE-OS 2659242 (1976).

  3. R. Ran, D. FU, J. Macromol. Sci.-Chem.A27 (1990) 625.

    Google Scholar 

  4. J.R. Grawe, B.G. Bufkin, J. Coatings Technol.52 (1980) 52.

    Google Scholar 

  5. S. Masuda, M. Tanaka, T. Ota, J. Polym. Sci., Part A: Polym. Chem.27 (1989) 855.

    Google Scholar 

  6. J. Macromol. Sci.-Pure Appl. Chem.A 29 (1992) 821.

    Google Scholar 

  7. T. Sato, N. Morita, H. Tanaka, T. Ota, Makromol. Chem.191 (1990) 2599.

    Google Scholar 

  8. T. Sato, N. Morita, I. Kamiyama, H. Tanaka, T. Oda, Makromol. Chem., Rapid Commun.11 (1990) 553.

    Google Scholar 

  9. K. Körber, K. Ludwig, Zahnärztliche Werkstoffkunde und Technologie, G. Thieme Verlag, Stuttgart-New York 1982, 168.

    Google Scholar 

  10. G.M. Brauer E.E. White, M.G. Moshonas, J. Dent. Res.37 (1958) 547.

    PubMed  Google Scholar 

  11. T.L. Nielsen, Acta Odont. Scand.21 (1963) 159.

    PubMed  Google Scholar 

  12. N. Moszner, M. Hartmann, P. Zalusky, D. Vegh and J. Kovac: J. Macromol. Sci.-Chem.A-27 (1990) 59.

    Google Scholar 

  13. W. Connely, G. Moddy, R.O. Symcox, GB-Patent 1144486 (1967).

  14. R. West, R. Riley, J. Inorg. Nucl. Chem.5 (1958) 295.

    Google Scholar 

  15. W.C. Fernelius, B.E. Bryant, Inorg. Synth.5 (1958) 295.

    Google Scholar 

  16. R.C. Mehrotra, R. Bohra, D.P. Gaur, Metal-β-Diketonates and Allied Derivatives, Academic, London 1978.

    Google Scholar 

  17. H.G. Brittain, Inorg. Chem.14 (1975) 2858.

    Google Scholar 

  18. H. Friebolin, Ein- und zweidimensionale NMR-Spektroskopie, VCH Verlags-gesellschaft mbH, Weinheim/Basel/Cambridge/New York 1988, 144.

    Google Scholar 

  19. J. Lecomte, Disc. Faraday Soc.9 (1950) 125.

    Google Scholar 

  20. H.F. Holtzclaw, J. Collman, J. Amer. Chem. Soc.79 (1957) 3318.

    Google Scholar 

  21. R. West, R. Riley, J. Inorg. Nucl. Chem.5 (1958) 295.

    Google Scholar 

  22. R.N. Prasad, M. Jindal, Synth. React. Inorg. Met.-Org. Chem.19 (1989) 997.

    Google Scholar 

  23. S. Tazuke, in: Progress in Polymer Science Japan (Ed. M. Imoto and S. Onogo), Vol. 1, Tokio/New York 1971, 69

  24. P.L. Nayak, S. Lenka, J. Macromol. Sci.-Rev. Macromol. Chem.C-19 (1980) 83.

    Google Scholar 

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Authors and Affiliations

  1. Ivoclar AG, Bendererstrasse 2, FL-9494, Schaan, Liechtenstein

    Norbert Moszner, Ulrich Salz & Volker Rheinberger

Authors
  1. Norbert Moszner
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  2. Ulrich Salz
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  3. Volker Rheinberger
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Moszner, N., Salz, U. & Rheinberger, V. Reaction behaviour of monomeric β-ketoesters. Polymer Bulletin 32, 411–417 (1994). https://doi.org/10.1007/BF00587882

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  • DOI: https://doi.org/10.1007/BF00587882

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