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Preparation and cure behavior of dimethacrylates containing oligo(tetrafluoroethene) segments

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Summary

Two novel families of dimethacrylate-based thermoset resins containing oligo(tetrafluoroethene) segments with n=1, 2, 3 tetrafluoroethene units were prepared from dimethyl tetrafluorosuccinate, dimethyl octafluoroadipate and dimethyl dodecafluorosuberate. Methacrylate functionalities were determined using1H-NMR spectroscopy. Photocrosslinking by UV irradiation in the presence of photoinitiators affords amorphous networks. The influence of the oligo(tetrafluoroethene) segment length on glass transition temperatures, swelling, volume shrinkage and thermal degradation was investigated.

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References

  1. Plunkett RJ in Seymour RB, Kirshenbaum GS (eds.) “High Performance Polymers: Their Origin and Development”, Elsevier Publ. Co. Inc., New York 1986, p.261–266

    Google Scholar 

  2. Kotov S, Ivanov G, Kostov G (1988) J Fluor Chem 41: 293

    Article  Google Scholar 

  3. Haszeldine RN (1951) Nature 167: 139

    PubMed  Google Scholar 

  4. Millauer H (1988) DECHEMA Monogr 112: 429

    Google Scholar 

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Authors and Affiliations

  1. Freiburger Materialforschungszentrum, Stefan-Meier-Strasse 31, D-79104, Freiburg, Germany

    Norbert Steinhauser & Rolf Mülhaupt

  2. Institut für Makromolekulare Chemie, Stefan-Meier-Strasse 31, D-79104, Freiburg, Germany

    Norbert Steinhauser & Rolf Mülhaupt

Authors
  1. Norbert Steinhauser
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  2. Rolf Mülhaupt
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Steinhauser, N., Mülhaupt, R. Preparation and cure behavior of dimethacrylates containing oligo(tetrafluoroethene) segments. Polymer Bulletin 32, 403–410 (1994). https://doi.org/10.1007/BF00587881

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  • DOI: https://doi.org/10.1007/BF00587881

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