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Micro determination of olefinic unsaturation. Reaction of N-bromosuccinimide with olefins in polar medium

Mikrobestimmung der Ungesättigtheit von Olefinen. Reaktion von N-Bromsuccinimid mit Olefinen in polarem Medium

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Zusammenfassung

2–10mg der Probe werden in Essigsäure gelöst, mit überschüssigem Reagens versetzt und der Überschuß jodometrisch zurücktitriert. Der maximale Fehler der Ergebnisse beträgt ±2%. Verbindungen, die benachbart zur C=C-Doppelbindung elektronenentziehende Gruppen enthalten, können nicht analysiert werden.

Summary

A micro method for the determination of olefinic unsaturation in organic compounds has been developed. 2–10 mg sample dissolved in acetic acid is reacted with a known excess of N-bromosuccinimide at room temperature and the excess reagent is back titrated iodometrically. The maximum deviation in the results is ±2%. The compounds containing electron withdrawing groups close to the C=C site are not reactive and hence could not be determined by this procedure.

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References

  1. Barakat, M. Z., Abd-El Wahab, M. F.: Anal. Chem.26, 1973 (1954); cf. Z. Anal. Chem.148, 298 (1956/56).

    Article  CAS  Google Scholar 

  2. Djerassi, C.: Chem. Rev.43, 271 (1948).

    Article  CAS  Google Scholar 

  3. Filler, R.: Chem. Rev.62, 21–43 (1963).

    Article  Google Scholar 

  4. Tiwari, R. D., Sharma, J. P., Shukla, I. C.: Talanta14, 853–856 (1967).

    Article  CAS  Google Scholar 

  5. Trischler, F., Szivos, K.: Magyar Kemiai Folyoirat72(5), 203–205 (1966); cf. Anal. Chem.233, 307 (1968).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Allahabad, Allahabad, India

    V. K. S. Shukla, U. C. Pande & J. P. Sharma

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  1. V. K. S. Shukla
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  2. U. C. Pande
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  3. J. P. Sharma
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Shukla, V.K.S., Pande, U.C. & Sharma, J.P. Micro determination of olefinic unsaturation. Reaction of N-bromosuccinimide with olefins in polar medium. Z. Anal. Chem. 260, 359–361 (1972). https://doi.org/10.1007/BF00585258

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  • DOI: https://doi.org/10.1007/BF00585258

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