Chemistry of Natural Compounds

, Volume 18, Issue 1, pp 66–69 | Cite as

Stereoisomerism of the matrine alkaloids

  • B. T. Ibragimov
  • G. N. Tishchenko
  • Yu. K. Kushmuradov
  • S. A. Talinov
  • T. F. Aripov
Article

Abstract

The stereoisomerism of compounds of the matrine series is considered on the basis of the authors' own x-ray structural studies of these alkaloids. A corrected series of eight stereoisomers has been drawn up. It has been shown that the numbers of theoretically possible stereoisomers of matrine is thirty-two.

Keywords

Alkaloid Matrine Relative Configuration Asymmetric Center Asymmetric Carbon Atom 

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Literature cited

  1. 1.
    H. Kondo and V. Sato, J. Pharm. Soc. Jpn.,41, 1 (1921).Google Scholar
  2. 2.
    B. T. Ibragimov, S. A. Talipov, G. N. Tishenko, Yu. K. Kushmuradov, and T. F. Aripov, Kristallografiya,23, 1189 (1978).Google Scholar
  3. 3.
    F. Bohlmann, W. Weise, D. Rahtz, and Ch. Arndt, Chem. Ber.,91, 2176 (1958).CrossRefGoogle Scholar
  4. 4.
    A. Ueno, K. Morinaga, S. Fukushima, Y. Iitaka, Y. Koiso, and S. Okuda, Chem. Pharm. Bull.,23, 2560 (1975).Google Scholar
  5. 5.
    B. T. Ibragimov, G. N. Tishenko, Yu. K. Kushmuradov, T. F. Aripov, and A. S. Sadykov, Khim. Prir. Soedin., 416 (1979).Google Scholar
  6. 6.
    B. T. Ibragimov, G. N. Tishenko, Yu. K. Kushmuradov, T. F. Aripov, and A. S. Sadykov, Khim. Prir. Soedin., 355 (1979).Google Scholar
  7. 7.
    B. T. Ibragimov, S. A. Talipov, G. N. Tishchenko, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 586 (1979).Google Scholar
  8. 8.
    B. T. Ibragimov, S. A. Talipov, G. N. Tishchenko, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 588 (1979).Google Scholar
  9. 9.
    B. T. Abragimov, S. A. Talipov, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 597 (1981).Google Scholar
  10. 10.
    F. G. Kamaev, V. B. Leont'ev, Kh. A. Aslamov, Yu. V. Ustynyuk, and A. S. Sadykov, Khim. Prir. Soedin., 744 (1974).Google Scholar
  11. 11.
    T. E. Monakhova, O. N. Tolkachev, V. E. Kabanov, M. E. Perel'son, and N. F. Proskurnina, Khim. Prir. Soedin., 472 (1974).Google Scholar
  12. 12.
    S. Zunnunzhanov, S. Iskandarov, and S. Yu. Yunusov, Khim. Prir. Soedin., 851 (1971).Google Scholar
  13. 13.
    R. S. Cahn, C. Ingold, and V. Prelog, Angew. Chem. Int. Ed.,5, 385 (1966).CrossRefGoogle Scholar
  14. 14.
    I. C. Schwartz, Chem. Commun., 505 (1973).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • B. T. Ibragimov
  • G. N. Tishchenko
  • Yu. K. Kushmuradov
  • S. A. Talinov
  • T. F. Aripov

There are no affiliations available

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