Conclusions
The effect of surface-active substances on the synthesis of fibre-forming acrylonitrile copolymers in aqueous sodium thiocyanate solutions has been studied.
Increasing the content of surface-active substances in the reaction medium leads to a decrease in the overall activation energy of the copolymerization reaction and to a certain increase in the molecular weight of the copolymer.
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Literature cited
P. P. Pugachevich and A. G. Tokaev, Dokl. Akad. Nauk SSSR,189, 577 (1969).
V. I. Myshko, R. A. Veselovskii, and Yu. S. Lipatov, Vysokomol. Soedin., Ser. B,13, No. 2, 114–117 (1971).
A. Jenkins and A. Ledwith (editors), Reactivity, Mechanism, and Structure in Polymer Chemistry, Wiley (1974).
N. L. Kuz'mina and I. S. Rabinovich, Khim. Volokna, No. 2, 64–65 (1971).
V. V. Krasil'nikov, N. L. Kuz'mina, I. S. Rabinovich, and Yu. M. Malyshev, Khim. Volokna, No. 8, 17–14 (1974).
S. I. Slepakova and B. E. Geller, Khim. Volokna, No. 2, 18–19 (1982).
J. M. Parker, P. V. Wright, and C. C. Lee, Polymer,22, No. 10, 1305–1307 (1981).
P. P. Pugachevich, É. M. Belyarov, and I. A. Lavygin, Surface Phenomena in Polymers [in Russian], Khinmiya, Moscow (1982).
Additional information
Translated from Khimicheskie Volokna, No. 3, pp. 26–27, May–June, 1985.
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Malyshev, Y.M., Geller, B.É. Effect of surface-active substances on the synthesis of fibre-forming acrylonitrile copolymers. Fibre Chem 17, 176–177 (1986). https://doi.org/10.1007/BF00581447
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DOI: https://doi.org/10.1007/BF00581447