Skip to main content
Log in

Ultraviolet absorption of flavonoids IV. Protonation constants of some monohydroxy flavones

  • Published:
Chemistry of Natural Compounds Aims and scope

Summary

1. The protonation constants of flavone, 3-hydroxyflavone and its methyl ether, and 7-, 5-, and 4′-hydroxyflavones have been determined by a spectrophotometric method.

2. It has been shown that the basicities of the monohydroxyflavones change fundamentally according to the position of electron-donating substituents in the molecule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. N. A. Tyukavkina, N. N. Pogodaeva, and V. I. Lutskii, Khim. Prirodn. Soedin., 24 (1970).

  2. N. A. Tyukavkina and N. N. Pogodaeva, Khim. Prirodn. Soedin., 11 (1971).

  3. N. A. Tyukavkina and N. N. Pogodaeva, Khim. Prirodn. Soedin., 173 (1972).

  4. A. I. Tolmachev, L. M. Shulezhko, and A. A. Kisilenko, Zh. Obshch. Khim.,35, 1707 (1965).

    CAS  Google Scholar 

  5. A. I. Tolmachev, L. M. Shulezhko, and A. A. Kisilenko, Zh. Obshch. Khim.,38, 118 (1968).

    CAS  Google Scholar 

  6. A. I. Tolmachev, Zh. N. Belaya, and L. M. Shulezhko, Zh. Obshch. Khim.,38, 1139 (1968).

    CAS  Google Scholar 

  7. A. I. Tolmachev, G. G. Dyadyusha, and L. M. Shulezhko, Teoret. i Éksperim. Khim.,6, 185 (1970).

    CAS  Google Scholar 

  8. C. T. Davies and T. A. Geissman, J. Amer. Chem. Soc.,76, 3507 (1954).

    Article  Google Scholar 

  9. E. M. Arnett and C. Y. Wu, J. Amer. Chem. Soc.,82, 5660 (1960).

    Article  CAS  Google Scholar 

  10. D. Noyce and M. Jorgenson, J. Amer. Chem. Soc.,84, 3412 (1962).

    Google Scholar 

  11. V. A. Pal'm, Principles of the Quantitative Theory of Organic Reactions [in Russian], Khimiya, Leningrad (1967), p. 318.

    Google Scholar 

  12. L. Bellamy, Advances in Infrared Group Frequencies, Methuen, London (1968).

    Google Scholar 

  13. J. H. Looker and W. W. Hanneman, J. Org. Chem.,27, 381 (1962).

    Article  CAS  Google Scholar 

  14. K. Doerfel, Z. Anal. Chem.,185, 1 (1962).

    Article  Google Scholar 

Download references

Authors

Additional information

Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 25–28, January–February, 1973.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pogodaeva, N.N., Tyukavkina, N.A. Ultraviolet absorption of flavonoids IV. Protonation constants of some monohydroxy flavones. Chem Nat Compd 9, 22–24 (1973). https://doi.org/10.1007/BF00580881

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00580881

Keywords

Navigation