Abstract
A new sesquiterpene — 14-hydroxycaryophyllene 4,5-oxide — has been isolated from the unsaponifiable part of an ethereal extract of the leaves ofBetula pubescens, and its structure has been established on the basis of chemical and spectral characteristics.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
N. D. Pokhilo, V. A. Denisenko, V. V. Makhan'kov, and N. I. Uvarova, Khim. Prir. Soedin., 392 (1983).
H. Beierbeck, J. K. Saunders, and J. W. ApSimon, Can. J. Chem.,55, 2813 (1977).
V. Srinivasan and E. W. Warnhoff, Can. J. Chem.,54, 1372 (1976).
R. F. Raffauf, M. P. Pastore, C. J. Kelley, P. W. LeQuesne, I. Miura, K. Nakanishi, J. Finer, and J. Clardy, J. Am. Chem. Soc.,100, 7437 (1978).
A. Groweiss and Y. Kashman, Tetrahedron Lett., 2205 (1978).
T. Yoshida, J. Nobuhara, M. Uchida, and T. Okuda, Chem. Pharm. Bull.,26, 2535 (1978).
W. Vichewski, A. P. Lins, W. Herz, and R. Murari, Phytochemistry,19, 685 (1980).
F. Bohlmann, C. Zdero, H. Robinson, and R. M. King, Phytochemistry,19, 2381 (1980).
A. Ahond, B. F. Bowden, J. C. Coll, J.-D. Fourneron, and S. J. Mitchell, Aust. J. Chem.,34, 2657 (1981).
F. C. Fischer and N. Seiler, Ann. Chem.,626, 185 (1959).
Additional information
Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 598–603, September–October, 1984.
Rights and permissions
About this article
Cite this article
Pokhilo, N.D., Denisenko, V.A., Novikov, V.L. et al. 14-Hydroxycaryophyllene 4,5-oxide — A new sesquiterpene fromBetula pubescens . Chem Nat Compd 20, 563–567 (1984). https://doi.org/10.1007/BF00580066
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00580066