Abstract
Three new cinnamyl alcohol glycosides have been isolated for the first time from the rhizomes of roseroot stonecropRhodiola rosea L. (Sedum rosea). On the basis of chemical transformations and the results of UV, IR, PMR, and mass spectroscopy the following structures are proposed for the compounds isolated: rozin — trans-cinnamyl O-β-D-glucopyranoside; rozavin — transcinnamyl O-(6′-O-α-L-arabinopyranosyl-β-D-glucopyranoside); and rozarin — trans-cinnamyl O-(6′-O-α-L-arabinofuranosyl-β-glucopyranoside).
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Literature cited
V. A. Kurkin, G. G. Zapesochnaya, and V. G. Klyazinka, Khim. Prir. Soedin., 581 (1982).
H. Schwarz, C. Köppel, and F. Bohlmann, Org. Mass. Spectrom.,7, 881 (1973).
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G. G. Zapesochnaya, Khim. Prir. Soedin., 21 (1979).
Additional information
All-Union Scientific-Research Institute of Medicinal Plants, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 723–727, November–December, 1982.
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Zapesochnaya, G.G., Kurkin, V.A. Glycosides of cinnamyl alcohol from the rhizomes ofRhodiola rosea . Chem Nat Compd 18, 685–688 (1982). https://doi.org/10.1007/BF00579423
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DOI: https://doi.org/10.1007/BF00579423
Keywords
- Cinnamyl
- Cinnamyl Alcohol
- Arabinose Residue
- Rhodiola Rosea
- Glucopyranose Residue