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Chemistry of Natural Compounds

, Volume 21, Issue 5, pp 570–578 | Cite as

13C NMR spectra of biologically active compounds. II. 11-Deoxy-16- and 17-aryloxyprostaglandins

  • G. A. Tolstikov
  • L. M. Khalilov
  • A. A. Panasenko
  • M. A. Danilova
  • M. S. Miftakov
Article
  • 25 Downloads

Abstract

The13C NMR spectra of the initial ω-aryloxy chains and the final 16-and 17-aryloxyprostaglandins of the 11-deoxy series have been investigated, and stereochemical assignments have been made for the diastereomeric pairs. A weakening of the diastereotopic effects in the spectra of the 15- and 16-methyl-substituted 16- and 17-phenoxypropstaglandins to 0.1 ppm has been shown.

Keywords

Carbon Atom Trans Isomer Chiral Center Butyl Ester Trimethylsiloxy 

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • G. A. Tolstikov
  • L. M. Khalilov
  • A. A. Panasenko
  • M. A. Danilova
  • M. S. Miftakov

There are no affiliations available

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