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13C NMR spectra of biologically active compounds. II. 11-Deoxy-16- and 17-aryloxyprostaglandins

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Abstract

The13C NMR spectra of the initial ω-aryloxy chains and the final 16-and 17-aryloxyprostaglandins of the 11-deoxy series have been investigated, and stereochemical assignments have been made for the diastereomeric pairs. A weakening of the diastereotopic effects in the spectra of the 15- and 16-methyl-substituted 16- and 17-phenoxypropstaglandins to 0.1 ppm has been shown.

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Authors
  1. G. A. Tolstikov
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  2. L. M. Khalilov
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  3. A. A. Panasenko
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  4. M. A. Danilova
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  5. M. S. Miftakov
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Additional information

Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 610–618, September–October, 1985.

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Tolstikov, G.A., Khalilov, L.M., Panasenko, A.A. et al. 13C NMR spectra of biologically active compounds. II. 11-Deoxy-16- and 17-aryloxyprostaglandins. Chem Nat Compd 21, 570–578 (1985). https://doi.org/10.1007/BF00579054

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  • DOI: https://doi.org/10.1007/BF00579054

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