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Self-propagating high-temperature synthesis

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Abstract

Self-propagating high-temperature synthesis (SHS) and processes based on SHS are currently being developed the world over for the production of powders and near-net shape components of advanced materials. The research activities that have been and are being carried out in this field are reviewed here. Theoretical principles underlying SHS process, such as equlibrium computation and kinetics involving heat and mass transfer are described. General concepts about the SHS reaction mechanisms with a few illustrative examples are presented. Along with a detailed description of the processing techniques such as powder production,in situ consolidation and casting, a few of the novel techniques based on SHS are also elaborated.

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Abbreviations

C p :

Combined heat capacity of the products

D :

Diffusion coefficient,D=D o e−(E/RT)

E :

Activation energy

f :

Fraction melted

ΔH r To ,Q :

Enthalpy of the reaction at temperature,T o

k :

Reaction rate constant,k=k e−(E/RT)

n :

Order of the reaction

p B :

Partial pressure of the reactant gas B

R :

Universal gas constant

S :

Surface area of the solid reactant

T ad :

Adiabatic temperature

T o :

Initial temperature

T m :

Melting point

T b :

Boiling point

v :

Velocity of wave propagation

α:

Thermal diffusivity

αc :

Parameter delineating combustion regimes

η:

Fraction converted

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  1. Defence Metallurgical Research Laboratory, Combustion Synthesis Group, 500 258, Hyderabad, India

    J. Subrahmanyam & M. Vijayakumar

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  1. J. Subrahmanyam
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Subrahmanyam, J., Vijayakumar, M. Self-propagating high-temperature synthesis. J Mater Sci 27, 6249–6273 (1992). https://doi.org/10.1007/BF00576271

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