Abstract
An x-ray structural examination of 3-mercapto-2-benzo [b] furylidene-(p-methyl-phenyl) amine has been carried out. For the first time, the position of the bridge hydrogen atom in a mercaptoaldimine containing the planar conjugated S=C-C=C-N grouping closed by an intramolecular N-H...S hydrogen bond has been established.
Similar content being viewed by others
Literature cited
V. P. Litvinov, V. A. Petukhov, V. Yu. Mortikov, and A. F. Vaisburg, Khim. Geterotsikl. Soedin., No. 6, 774 (1986).
L. A. Kazitsina, N. B. Kupletskaya, L. L. Polstyanko, B. S. Kilot', and A. P. Tarent'ev, Zh. Obshch. Khim.,31, 313 (1961).
W. F. Richey and R. S. Becher, J. Chem. Phys.,49, 2092 (1968).
V. I. Minkin, L. P. Olekhnovich, L. E. Nivorozhkin, Yu. A. Zhdanov, and M. I. Knyazhanskii, Zh. Org. Khim.,6, 348 (1970).
V. P. Litvinov, Ya. L. Gol'dfarb, and É. G. Ostapenko, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2279 (1974).
V. A. Bren', V. I. Usacheva, Zh. V. Bren', B. Ya. Simkin, and V. I. Minkin, Khim. Geterotsikl. Soedin., No. 5, 631 (1974).
V. S. Bogdanov, M. A. Kalik, I. P. Yakovlev, and Ya. L. Gol'dfarb, Zh. Obshch. Khim.,40, 2102 (1970).
L. G. Kuz'mina, Yu. T. Struchkov, M. A. Kalik, and Ya. L. Gol'dfarb, Khim. Geterotsikl. Soedin., No. 12, 1625 (1978).
R. N. Nurmukhametov, O. I. Betin, and D. N. Shigorin, Dokl. Akad. Nauk SSSR,230, 146 (1976).
L. N. Kurkovskaya, R. N. Nurmukhametov, and D. N. Shigorin, Zh. Strukt. Khim.,21, 61 (1980).
H. W. Kroto and B. M. Landsberg, J. Mol. Spectr.,62, 346 (1976).
G. Pepe and M. Pierrot, Acta Cryst.,B32, 1321 (1976).
A. I. Kitaigorodsky, Molecular Crystals and Molecules, Academic Press, New York (1973), p. 431.
International Tables for X-Ray Crystallography, Kynoch Press, Birmingham (1968), Vol. 3, p. 276.
R. Fourme, Acta Cryst.,B28. 2984 (1972).
E. Ya. Lukevits (Ed.), Advances in Furan Chemistry [in Russian], Zinatne, Riga (1978), p. 15.
A. Bondi, J. Phys. Chem.,70. 3006 (1966).
A. F. Vaisburg, V. Yu. Mortikov, and V. P. Litvinov, Khim. Geterotsikl. Soedin., No. 5, 598 (1985).
R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov, Kristallografiya,28, 1029 (1983).
Author information
Authors and Affiliations
Additional information
For communication 45, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 779–782, June, 1986.
Rights and permissions
About this article
Cite this article
Nesterov, V.N., Shklover, V.E., Struchkov, Y.T. et al. Condensed heterocycles. 46. Crystal structure of 3-mercapto-2-benzo[b]-furylidene-(p-methylphenyl) amine. Chem Heterocycl Compd 22, 613–616 (1986). https://doi.org/10.1007/BF00575240
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00575240